Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
| Facile synthesis of copper ions chelated sand via dopamine chemistry for recyclable and sustainable catalysis | |
Wang, N; Zhang, ZR; Huang, JR; Hu, YX
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| 发表期刊 | CHEMICAL ENGINEERING SCIENCE
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| ISSN | 0009-2509 |
| 2019-08-10 | |
| 卷号 | 203页码:312-320 |
| 关键词 | Cu ions Dopamine Catalytic reduction Organic dyes Color removal |
| 研究领域 | Engineering, Chemical |
| DOI | 10.1016/j.ces.2019.04.009 |
| 产权排序 | [Wang, Ning; Zhang, Zhongren] Chinese Acad Sci, Yantai Inst Coastal Zone Res, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China; [Huang, Juanru; Hu, Yunxia] Tianjin Polytech Univ, State Key Lab Separat Membranes & Membrane Proc, Natl Ctr Int Res Membrane Sci & Technol, Sch Mat Sci & Engn, Tianjin 300387, Peoples R China |
| 通讯作者 | Hu, Yunxia(yunxiahu@yic.ac.cn) |
| 作者部门 | 中国科学院海岸带环境过程重点实验室 |
| 英文摘要 | Metal-based catalysts present highly efficient catalytic activities towards organic dyes and their intermediates for color removal. However, several issues are needed to be addressed urgently for their large-scale practical applications, such as the cost, stability and recyclable use of these catalysts. In this work, we developed a facile approach to chelate Cu ions on the polydopamine-coated sand (Cu-PDA@Sand) and investigated their catalytic properties towards the decoloration of organic dyes or intermediate including 4-nitrophenol (4-NP), methylene blue (MB), and congo red (CR). Our results found that the copper ions from Cu-PDA@Sand were the mixture of Cu (I) and Cu (II), and the molar fraction of Cu (I) over Cu (II) was increased from the original 3:2 to 4:1 in the presence of NaBH4. The reduction of these organic dyes or intermediate followed the first order kinetics, and the apparent reduction rate k up of CR was larger than that of MB and 4-NP under similar conditions. Additionally, the optimized k up of 4-NP could reach to 1.28 min (1), which is much higher than the reported results from literature. The recyclability test of CuPDA@Sand showed that the reduction efficiency of Cu-PDA@Sand maintained 100% during the successive 20 cycles. Additionally, Cu-PDA@Sand was demonstrated to present long-term stability and catalytic activities after soaking Cu-PDA@Sand in water for 30 days. Our research demonstrated that the easy-prepared low-cost Cu-PDA@Sand catalyst would have a great potential in the practical applications for color removal of the dye-containing wastewater. (C) 2019 Elsevier Ltd. All rights reserved. |
| 文章类型 | Article |
| 资助机构 | National Natural Science Foundation of ChinaNational Natural Science Foundation of China [21476249] ; Chang-jiang Scholars and Innovative Research Team in the University of Ministry of Education, China [IRT-17R80] ; Program for Innovative Research Team in University of Tianjin [TD13-5044] ; Science and Technology Plans of Tianjin [17PT-SYJC00060] ; Key Science and Technology Program of Yantai City [2018ZHGY075] |
| 收录类别 | SCI |
| 语种 | 英语 |
| 关键词[WOS] | SITU GREEN SYNTHESIS ; SILVER NANOPARTICLES ; HIGHLY EFFICIENT ; AZO-DYE ; GOLD NANOPARTICLES ; AQUEOUS-SOLUTIONS ; HIGH-STABILITY ; REDUCTION ; REMOVAL ; 4-NITROPHENOL |
| 研究领域[WOS] | Engineering, Chemical |
| WOS记录号 | WOS:000465363600026 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.yic.ac.cn/handle/133337/24883 |
| 专题 | 中国科学院海岸带环境过程与生态修复重点实验室 中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心 |
| 作者单位 | 1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China; 2.Tianjin Polytech Univ, State Key Lab Separat Membranes & Membrane Proc, Natl Ctr Int Res Membrane Sci & Technol, Sch Mat Sci & Engn, Tianjin 300387, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, N,Zhang, ZR,Huang, JR,et al. Facile synthesis of copper ions chelated sand via dopamine chemistry for recyclable and sustainable catalysis[J]. CHEMICAL ENGINEERING SCIENCE,2019,203:312-320. |
| APA | Wang, N,Zhang, ZR,Huang, JR,&Hu, YX.(2019).Facile synthesis of copper ions chelated sand via dopamine chemistry for recyclable and sustainable catalysis.CHEMICAL ENGINEERING SCIENCE,203,312-320. |
| MLA | Wang, N,et al."Facile synthesis of copper ions chelated sand via dopamine chemistry for recyclable and sustainable catalysis".CHEMICAL ENGINEERING SCIENCE 203(2019):312-320. |
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