Development and application of diffusive gradients in thin films for in situ sampling of the organic UV filter 4-methylbenzylidene camphor (4-MBC) in waters

doi:10.1007/s11356-023-28844-8

	Development and application of diffusive gradients in thin films for in situ sampling of the organic UV filter 4-methylbenzylidene camphor (4-MBC) in waters
	Ren, Suyu 1; Jin, Xiaojie 2; Bekele, Tadiyose Girma 3; Lv, Min4 ; Ding, Jing 1; Tan, Feng 3; Chen, Lingxin4
发表期刊	ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
ISSN	0944-1344
	2023-07-26
页码	11
关键词	Organic UV filters Diffusive gradients in thin films (DGT) Passive sampling Coastal waters
DOI	10.1007/s11356-023-28844-8
通讯作者	Tan, Feng(tanf@dlut.edu.cn)
英文摘要	4-Methylbenzylidene camphor (4-MBC), a typical organic UV filter (OUVF) in personal care products, is considered to be a potential endocrine disruptor due to its estrogenic activity and bioaccumulation. Although 4-MBC residues have been extensively identified in aquatic waters, little is known about their occurrence, levels, and potential risk in coastal waters. This study developed a reliable sampling approach, based on diffusive gradients in thin films (DGT) with XAD-2 as the binding agent, for monitoring 4-MBC in coastal waters. The diffusion coefficients of 4-MBC in freshwater and artificial seawater were 3.65 x 10(-6) cm(2)/s and 3.83 x 10(-6) cm(2)/s, respectively. XAD-2 binding gel showed rapid adsorption to 4-MBC. The accumulated masses of 4-MBC in XAD-2 DGT increased linearly with deployed time for 7 days in freshwater and seawater, which agreed well with theoretical predictions. The sampling performance was independent of ionic strength (0.0001-0.5 M), pH (4.0-8.5), and dissolved organic matter (0-20 mg/L). Field deployment in the river estuary and bathing beach showed that DGT-measured 4-MBC concentrations were consistent in comparison with grab sampling. Environmental risk assessment showed that 4-MBC may pose a medium risk to aquatic organisms based on computed risk quotient (RQ) values. Sewage discharge is the main source of 4-MBC risk, while the residue in recreation beaches contributes more significantly in summer. The established DGT sampling is suitable for seasonal monitoring, source identification, and risk assessment of 4-MBC in coastal waters.
资助机构	National Natural Science Foundation of China ; Open Foundation of Key Laboratory of Industrial Ecology and Environmental Engineering, MOE
收录类别	SCI
语种	英语
关键词[WOS]	ENDOCRINE DISRUPTING CHEMICALS ; PERSONAL CARE PRODUCTS ; WASTE-WATER ; ENVIRONMENTAL RISK ; SURFACE WATERS ; ANTIBIOTICS ; CALIBRATION ; GROWTH ; DGT
研究领域[WOS]	Environmental Sciences & Ecology
WOS记录号	WOS:001038378100007
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/33472
专题	中国科学院海岸带环境过程与生态修复重点实验室中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心
通讯作者	Tan, Feng
作者单位	1.Yantai Univ, Sch Environm & Mat Engn, Yantai 264005, Peoples R China 2.Shandong Marine Resource & Environm Res Inst, Yantai 264006, Peoples R China 3.Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn MOE, Dalian 116024, Peoples R China 4.Chinese Acad Sci, Yantai Inst Coastal Zone Res, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China
推荐引用方式 GB/T 7714	Ren, Suyu,Jin, Xiaojie,Bekele, Tadiyose Girma,et al. Development and application of diffusive gradients in thin films for in situ sampling of the organic UV filter 4-methylbenzylidene camphor (4-MBC) in waters[J]. ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,2023:11.
APA	Ren, Suyu.,Jin, Xiaojie.,Bekele, Tadiyose Girma.,Lv, Min.,Ding, Jing.,...&Chen, Lingxin.(2023).Development and application of diffusive gradients in thin films for in situ sampling of the organic UV filter 4-methylbenzylidene camphor (4-MBC) in waters.ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,11.
MLA	Ren, Suyu,et al."Development and application of diffusive gradients in thin films for in situ sampling of the organic UV filter 4-methylbenzylidene camphor (4-MBC) in waters".ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023):11.