Nanoporous platinum electrode grown on anodic aluminum oxide membrane: Fabrication, characterization, electrocatalytic activity toward reactive oxygen and nitrogen species | |
Tao, Wenyan; Pan, Dawei![]() | |
发表期刊 | ANALYTICA CHIMICA ACTA
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ISSN | 0003-2670 |
2018-12-04 | |
卷号 | 1035页码:44-50 |
关键词 | Nanoporous platinum electrode Nitric oxide Angeli's salt Thermal evaporation deposition |
研究领域 | Chemistry |
DOI | 10.1016/j.aca.2018.06.076 |
产权排序 | [Tao, Wenyan; Gong, Zanhua; Peng, Xia] Shenzhen Huachenyang Technol Co, Shenzhen 510081, Peoples R China; [Tao, Wenyan] Chinese Univ Hong Kong, Dept Elect Engn, Hong Kong, Hong Kong, Peoples R China; [Pan, Dawei] Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China; [Pan, Dawei] Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
作者部门 | 海岸带环境工程技术研究与发展中心 |
英文摘要 | A new type of nanoelectrode, nanoporous platinum (NPt) electrode was prepared on aluminum oxide membrane by thermal evaporation deposition. The morphology, conductivity and electrocatalytic activity of NPt electrode were characterized and compared with those of nanofilm-Pt electrode through scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) techniques, respectively. SEM images showed that "nanocavities" observed in NPt electrode were actually 2-dimensional enclosures by linked nanoparticles. It was different from the conventional arrays of "nanocavities" formed on homogeneous metal films. EIS data indicated that NPt electrode possesses higher conductivity. Compared with that on nanofilm-Pt electrode (14.05 Omega.cm(2)), the impedance spectrum on NPt electrode exhibits a semicircle portion with much smaller diameters (1.24 Omega.cm(2) for NPt-100, 1.48 Omega.cm(2) for NPt-200). Meanwhile, the response sensitivity of NPt electrode to O-2 is 0.85 mA cm(-2), which is larger than that of nanofilm-Pt electrode (0.54 mA cm(-2)). The largest catalytic current for nitric oxide (NO) was obtained in buffer with pH value of 9.4 while for Angeli's salt (AS) was obtained in buffer with pH value of 5.4. Additionally, electrocatalytic mechanisms of NPt electrode toward NO and AS were proposed, which indicating it depended on pH value of buffer solution. (C) 2018 Elsevier B.V. All rights reserved. |
文章类型 | Article |
资助机构 | National Natural Science Foundations of China [21405106] ; Youth Innovation Promotion Association of Chinese Academy of Sciences [2011170] ; Research and Development Foundation of Science and Technology of Shenzhen [JCYJ20150324141711592, 20180502154158198] |
收录类别 | SCI |
语种 | 英语 |
关键词[WOS] | SPECTROSCOPY ; NANOPARTICLES ; ARRAYS ; HNO |
研究领域[WOS] | Chemistry, Analytical |
WOS记录号 | WOS:000444918000005 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/24600 |
专题 | 中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心 |
作者单位 | 1.Shenzhen Huachenyang Technol Co, Shenzhen 510081, Peoples R China; 2.Chinese Univ Hong Kong, Dept Elect Engn, Hong Kong, Hong Kong, Peoples R China; 3.Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China; 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Tao, Wenyan,Pan, Dawei,Gong, Zanhua,et al. Nanoporous platinum electrode grown on anodic aluminum oxide membrane: Fabrication, characterization, electrocatalytic activity toward reactive oxygen and nitrogen species[J]. ANALYTICA CHIMICA ACTA,2018,1035:44-50. |
APA | Tao, Wenyan,Pan, Dawei,Gong, Zanhua,&Peng, Xia.(2018).Nanoporous platinum electrode grown on anodic aluminum oxide membrane: Fabrication, characterization, electrocatalytic activity toward reactive oxygen and nitrogen species.ANALYTICA CHIMICA ACTA,1035,44-50. |
MLA | Tao, Wenyan,et al."Nanoporous platinum electrode grown on anodic aluminum oxide membrane: Fabrication, characterization, electrocatalytic activity toward reactive oxygen and nitrogen species".ANALYTICA CHIMICA ACTA 1035(2018):44-50. |
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