Determination of 16 polycyclic aromatic hydrocarbons in environmental water samples by solid-phase extraction using multi-walled carbon nanotubes as adsorbent coupled with gas chromatography-mass spectrometry
Ma, Jiping1; Xiao, Ronghui1; Li, Jinhua2; Yu, Junbao2; Zhang, Yanqing1; Chen, Lingxin2
2010-08-20
Source PublicationJOURNAL OF CHROMATOGRAPHY A
ISSN0021-9673
Volume1217Issue:34Pages:5462-5469
Contribution Rank[Ma, Jiping; Xiao, Ronghui; Zhang, Yanqing] Qingdao Technol Univ, Inst Environm & Municipal Engn, Key Lab Environm Engn Shandong Prov, Qingdao 266033, Peoples R China; [Li, Jinhua; Yu, Junbao; Chen, Lingxin] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China
AbstractA solid-phase extraction (SPE) using multi-walled carbon nanotubes (MWCNTs) as adsorbent coupled with gas chromatography-mass spectrometry (GC-MS) method was developed for the determination of 16 polycyclic aromatic hydrocarbons (PAHs) in environmental water samples. Several condition parameters, such as extraction adsorbents, elution solvents and volumes, and sample loading flow rate and volume were optimized to obtain high SPE recoveries and extraction efficiency. 150 mg MWCNTs as sorbent presented high extraction efficiency of 16 PAHs due to the large specific surface area and high adsorption capacity of MWCNTs compared with the commercial C18 column (250 mg/2 mL). The calibration curves of 16 PAHs extracted were linear in the range of 20-5000 ng L-1, with the correlation coefficients (r(2)) between 0.9848 and 0.9991. The method attained good precisions (relative standard deviation, RSD) from 1.2% to 12.1% for standard PAHs aqueous solutions; method recoveries ranged in 76.0-125.5%, 74.5-127.0%, and 70.0-122.0% for real spiked samples from river water, tap water and seawater, respectively. Limits of detection (LODs, S/N = 3) of the method were determined from 2.0 to 8.5 ng L-1. The optimized method was successfully applied to the determination of 16 PAHs in real environmental water samples. (C) 2010 Elsevier B.V. All rights reserved.; A solid-phase extraction (SPE) using multi-walled carbon nanotubes (MWCNTs) as adsorbent coupled with gas chromatography-mass spectrometry (GC-MS) method was developed for the determination of 16 polycyclic aromatic hydrocarbons (PAHs) in environmental water samples. Several condition parameters, such as extraction adsorbents, elution solvents and volumes, and sample loading flow rate and volume were optimized to obtain high SPE recoveries and extraction efficiency. 150 mg MWCNTs as sorbent presented high extraction efficiency of 16 PAHs due to the large specific surface area and high adsorption capacity of MWCNTs compared with the commercial C18 column (250 mg/2 mL). The calibration curves of 16 PAHs extracted were linear in the range of 20-5000 ng L(-1), with the correlation coefficients (r(2)) between 0.9848 and 0.9991. The method attained good precisions (relative standard deviation, RSD) from 1.2% to 12.1% for standard PAHs aqueous solutions; method recoveries ranged in 76.0-125.5%, 74.5-127.0%, and 70.0-122.0% for real spiked samples from river water, tap water and seawater, respectively. Limits of detection (LODs, S/N = 3) of the method were determined from 2.0 to 8.5 ng L(-1). The optimized method was successfully applied to the determination of 16 PAHs in real environmental water samples. (C) 2010 Elsevier B.V. All rights reserved.
Corresponding AuthorMa, JP, Qingdao Technol Univ, Inst Environm & Municipal Engn, Key Lab Environm Engn Shandong Prov, Qingdao 266033, Peoples R China
KeywordPolycyclic Aromatic Hydrocarbons (Pahs) Solid-phase Extraction (Spe) Multi-walled Carbon Nanotubes (Mwcnts) Gas Chromatography-mass Spectrometry (Gc-ms) Water Samples
Department环境化学实验室 
Subject AreaBiochemical Research Methods ; Chemistry, Analytical
Funding OrganizationMinistry of Water Resources Public Welfare Specialized Research Foundation of China [200901063]; Education Commission Natural Science Foundation of Shandong Province [J07WZ05]; Qingdao Technological University [c2007-008]; Water Body Pollution Controlling and Treatment Significant Special Project Foundation of China Science and Technology [2009ZX07317-008-02]; Department of Science and Technology of Shandong Province of China [2008GG20005005]; CAS/SAFEA International Partnership Program for Creative Research Teams ; Chinese Academy of Sciences
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Indexed BySCI
WOS KeywordPERFORMANCE LIQUID-CHROMATOGRAPHY ; BAR SORPTIVE EXTRACTION ; TREATMENT-PLANT ; MICROEXTRACTION ; PAHS ; PENTACHLOROPHENOL ; GROUNDWATER ; ORGANOCLAY ; SEDIMENTS ; MUSSELS
SubtypeArticle
Language英语
WOS Research AreaBiochemistry & Molecular Biology ; Chemistry
WOS IDWOS:000281291000002
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Document Type期刊论文
Identifierhttp://ir.yic.ac.cn/handle/133337/3711
Collection中科院海岸带环境过程与生态修复重点实验室_环境化学实验室
Affiliation1.Qingdao Technol Univ, Inst Environm & Municipal Engn, Key Lab Environm Engn Shandong Prov, Qingdao 266033, Peoples R China
2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China
Recommended Citation
GB/T 7714
Ma, Jiping,Xiao, Ronghui,Li, Jinhua,et al. Determination of 16 polycyclic aromatic hydrocarbons in environmental water samples by solid-phase extraction using multi-walled carbon nanotubes as adsorbent coupled with gas chromatography-mass spectrometry[J]. JOURNAL OF CHROMATOGRAPHY A,2010,1217(34):5462-5469.
APA Ma, Jiping,Xiao, Ronghui,Li, Jinhua,Yu, Junbao,Zhang, Yanqing,&Chen, Lingxin.(2010).Determination of 16 polycyclic aromatic hydrocarbons in environmental water samples by solid-phase extraction using multi-walled carbon nanotubes as adsorbent coupled with gas chromatography-mass spectrometry.JOURNAL OF CHROMATOGRAPHY A,1217(34),5462-5469.
MLA Ma, Jiping,et al."Determination of 16 polycyclic aromatic hydrocarbons in environmental water samples by solid-phase extraction using multi-walled carbon nanotubes as adsorbent coupled with gas chromatography-mass spectrometry".JOURNAL OF CHROMATOGRAPHY A 1217.34(2010):5462-5469.
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