AU Nanoparticles Immobilized on Black Phosphorus Intercalated Spherical Covalent Organic Frameworks as Highly Active Catalysts for Flow-Through Reduction of 4-Nitrophenol
Xiao, Fengyan1; Pan, Dawei2,3,4; Wang, Ning2,3
发表期刊SSRN
ISSN15565068
2023
关键词Catalyst activity Microspheres Nanosheets Organic pollutants Phosphorus Synthesis (chemical)
DOI10.2139/ssrn.4525234
英文摘要The unique structure and morphology of covalent organic frameworks (COFs) show great potential as active substrates to support noble metals for catalytic application. However, the applications are restricted by their catalytic activity due to the weak conductivity of COFs. Here, conductive black phosphorus was intercalated inside the spherical COFs (SCOFs) during their synthesis process, followed by the immobilization of Au nanoparticles (Au NPs) to construct Au NPs/BP/SCOFs microspheres. A fast and stable flow-through catalysis towards 4-nitrophenol was obtained due to the design of conductive BP nanosheets intercalated SCOFs microspheres with enhanced electron transfer and stable structure. Our strategy to design the conductive BP nanosheets intercalated SCOFs microspheres would develop a new route to improve the catalytic activity for highly efficient conversion nitro-aromatic organic pollutants. © 2023, The Authors. All rights reserved.
收录类别EI
语种英语
EI主题词Catalyst activity ; Microspheres ; Nanosheets ; Organic pollutants ; Phosphorus ; Synthesis (chemical)
EI入藏号20230259135
引用统计
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/34308
专题中国科学院海岸带环境过程与生态修复重点实验室
中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心
作者单位1.Yantai Institute of Coastal Zone Research, China;
2.CAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Shandong, Yantai; 264003, China;
3.Shandong Key Laboratory of Coastal Environmental Processes, Shandong, Yantai; 264003, China;
4.University of Chinese Academy of Sciences, Beijing; 100049, China
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Xiao, Fengyan,Pan, Dawei,Wang, Ning. AU Nanoparticles Immobilized on Black Phosphorus Intercalated Spherical Covalent Organic Frameworks as Highly Active Catalysts for Flow-Through Reduction of 4-Nitrophenol[J]. SSRN,2023.
APA Xiao, Fengyan,Pan, Dawei,&Wang, Ning.(2023).AU Nanoparticles Immobilized on Black Phosphorus Intercalated Spherical Covalent Organic Frameworks as Highly Active Catalysts for Flow-Through Reduction of 4-Nitrophenol.SSRN.
MLA Xiao, Fengyan,et al."AU Nanoparticles Immobilized on Black Phosphorus Intercalated Spherical Covalent Organic Frameworks as Highly Active Catalysts for Flow-Through Reduction of 4-Nitrophenol".SSRN (2023).
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