The invention relates to a potential type micro electrode sensor, in particular to a potential type micro electrode sensor capable of being used for ion detection in settlings and application thereof.The potential type micro electrode sensor is a polymer film ion selective micro electrode, and consists of a gold micro electrode, a PEDOT (PSS) conduction layer and an iron selective polymer film; the iron selective polymer film is prepared by mixing ion selective carriers containing ions to be detected and lipophilic ion exchangers (quadri(3, 5-bis(trichloromethyl)phenyl)sodium borate accordingto the mol ratio of (1 : 2)-(1 : 4) and then adding polyvinyl chloride and o-nitrophenyl octyl ether. The solid contact type micro electrode has the advantages that the manufacturing is simple and convenient; the sensitivity is high; the cost is low; the miniaturization is easy, and the like. Meanwhile, the micro electrode mass transfer speed is high; the current density is great; the response speed is high, and the like. The ion field in-site analysis in settlings can be realized; the detection on various ions in the settings can be realized through changing the types of ion carriers in the ion selective films.
; 赵光涛; 秦伟
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