烟台夹河口外柱状沉积物还原性无机硫、活性铁的变化特征及其相互关系

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	烟台夹河口外柱状沉积物还原性无机硫、活性铁的变化特征及其相互关系
其他题名	Distribution characteristics and relationship between reduced inorganic sulfur and reactive iron in core sediments outside the mouth of the Jiahe River in Yantai
	姜明 ; 赵国强 ; 李兆冉 ; 盛彦清
发表期刊	海洋科学
ISSN	1000-3096
	2018
卷号	42 期号:8 页码:90-97
关键词	还原性无机硫活性铁深层柱状沉积物硫化度矿化度 Reduced inorganic sulfur Reactive iron Deep core sediments Degree of pyritization Degree of sulfidity The distribution characteristics and coupling mechanism of reduced inorganic sulfur (RIS)and reactive iron in marine core sediments are closely related to the evolution of environment quality.In this study,an improved cold diffusion method and hydrochloric acid extraction method were applied to the acid-volatile sulfur (AVS),pyrite sulfur (CRS),elemental sulfur (ES),and reactive iron [Fe (Ⅱ)and Fe (III)] analyses.The distribution characteristics and coupling mechanism of S and Fe were investigated based on a core sediment 4 meters deep collected in the northern sea area of the mouth of Jiahe River,Yantai.The results showed that the RIS in sediments was dominated by CRS,followed by AVS and ES.The content of AVS presented a narrow range with depth,whereas the CRS and ES were higher at the top and bottom layers than the middle layer reactive iron was dominated by Fe (II),which increased with depth,while Fe (Ⅲ)gradually decreased with depth.Most of the Fe (III)was reduced to the disssolved Fe(II),which was combined with the soluble H_2S of the sulfate-reducing bacteria to produce CRS and ES in the deep layer,resulting in their accumulation at the bottom of core sediments.Furthermore,this study showed that reactive iron was not a limiting factor for the accumulation of RIS with lower degree of pyritization and degree of sulfidity.
研究领域	Environmental Sciences & Ecology
产权排序	(1) 中国科学院烟台海岸带研究所山东省海岸带环境工程技术研究中心; (2) 中国科学院大学
作者部门	海岸带环境工程技术研究与发展中心
英文摘要	The distribution characteristics and coupling mechanism of reduced inorganic sulfur (RIS)and reactive iron in marine core sediments are closely related to the evolution of environment quality.In this study,an improved cold diffusion method and hydrochloric acid extraction method were applied to the acid-volatile sulfur (AVS),pyrite sulfur (CRS),elemental sulfur (ES),and reactive iron [Fe (Ⅱ)and Fe (III)] analyses.The distribution characteristics and coupling mechanism of S and Fe were investigated based on a core sediment 4 meters deep collected in the northern sea area of the mouth of Jiahe River,Yantai.The results showed that the RIS in sediments was dominated by CRS,followed by AVS and ES.The content of AVS presented a narrow range with depth,whereas the CRS and ES were higher at the top and bottom layers than the middle layer;reactive iron was dominated by Fe (II),which increased with depth,while Fe (Ⅲ)gradually decreased with depth.Most of the Fe (III)was reduced to the disssolved Fe(II),which was combined with the soluble H_2S of the sulfate-reducing bacteria to produce CRS and ES in the deep layer,resulting in their accumulation at the bottom of core sediments.Furthermore,this study showed that reactive iron was not a limiting factor for the accumulation of RIS with lower degree of pyritization and degree of sulfidity.
中文摘要	海洋沉积物中还原性无机硫和活性铁的地球化学过程与沉积物环境质量演变密切相关.本研究利用改进的冷扩散法和盐酸萃取法分别对烟台夹河口北部海域深约4m的柱状沉积物中的酸性可挥发硫(AVS)、黄铁矿硫(CRS)、元素硫(ES)和活性铁(FeII和FeⅢ)进行了测定,并从地球化学机理方面探讨了硫与铁的分布特征及其耦合机制.结果表明,烟台夹河口北部近海深层柱状沉积物中还原性无机硫以CRS为主,其次是AVS和ES,其中AVS含量垂向分布较均匀,而CRS和ES含量在垂向上呈表层和底层高,中间层低的趋势;活性铁以Fe(II)为主,其随深度增加而增加,Fe(Ⅲ)随深度逐渐降低,大部分Fe(Ⅲ)被还原为溶解态的Fe(Ⅱ),并且与硫酸盐还原产生的H_2S相结合生成CRS和ES,导致CRS和ES在柱状沉积物底部积累;同时研究表明,较低的硫化度和矿化度,活性铁不是还原性无机硫累积的限制因子.
资助机构	国家自然科学基金 ; 中国科学院关键技术人才项目
收录类别	CSCD
语种	中文
关键词[WOS]	还原性无机硫 ; 活性铁 ; 深层柱状沉积物 ; 硫化度 ; 矿化度 ; Reduced inorganic sulfur ; Reactive iron ; Deep core sediments ; Degree of pyritization ; Degree of sulfidity
研究领域[WOS]	Environmental Sciences & Ecology
CSCD记录号	CSCD:6435667
引用统计
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/25165
专题	中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心中国科学院海岸带环境过程与生态修复重点实验室
作者单位	1.中国科学院烟台海岸带研究所山东省海岸带环境工程技术研究中心; 2.中国科学院大学
推荐引用方式 GB/T 7714	姜明,赵国强,李兆冉,等. 烟台夹河口外柱状沉积物还原性无机硫、活性铁的变化特征及其相互关系[J]. 海洋科学,2018,42(8):90-97.
APA	姜明,赵国强,李兆冉,&盛彦清.(2018).烟台夹河口外柱状沉积物还原性无机硫、活性铁的变化特征及其相互关系.海洋科学,42(8),90-97.
MLA	姜明,et al."烟台夹河口外柱状沉积物还原性无机硫、活性铁的变化特征及其相互关系".海洋科学 42.8(2018):90-97.

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