| Hydrophilic molecularly imprinted nanospheres for the extraction of rhodamine B followed by HPLC analysis: A green approach and hazardous waste elimination | |
Arabi, Maryam; Ostovan, Abbas; Bagheri, Ahmad Reza; Guo, Xiaotong; Li, Jinhua ; Ma, Jiping; Chen, Lingxin
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| Source Publication | TALANTA
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| 2020-08-01 | |
| Volume | 215Pages:120933 |
| Keyword | POROUS CARBON MICROSPHERES SOLID-PHASE EXTRACTION HYDROTHERMAL SYNTHESIS SYNTHESIS STRATEGY RECOGNITION POLYMERS SURFACE BIOCOMPATIBILITY ENRICHMENT COMPOSITE |
| MOST Discipline Catalogue | Chemistry, Analytical |
| DOI | 10.1016/j.talanta.2020.120933 |
| Contribution Rank | [Arabi, Maryam; Ostovan, Abbas; Guo, Xiaotong; Li, Jinhua; Chen, Lingxin] Chinese Acad Sci, Res Ctr Coastal Environm Engn & Technol, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China; [Bagheri, Ahmad Reza] Univ Yasuj, Chem Dept, Yasuj 7591874831, Iran; [Ma, Jiping] Qingdao Univ Technol, State Local Joint Engn Res Ctr Urban Sewage Treat, Sch Environm & Municipal Engn, Qingdao 266033, Peoples R China; [Chen, Lingxin] Qufu Normal Univ, Dept Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China; [Guo, Xiaotong] Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Department | 海岸带环境工程技术研究与发展中心 |
| Abstract | In this work, hydrophilic molecularly imprinted nanospheres (MINs) were synthesized via surface imprinting technology and subsequently utilized as dispersant sorbent in matrix solid phase dispersion (MSPD) for the extraction of rhodamine B (RhB) as the illogical food additive dye from different foodstuffs, followed by HPLC analysis. By considering hydrophilicity of target analyte, the sol-gel route was chosen for the preparation of MINs in aqueous media at mild conditions. Most importantly, both synthesis and extraction steps were designed and performed in the line of green chemistry and hazardous waste was eliminated to minimize detrimental impact on the operator health and the environment. The reputable experimental design methodology was adopted to assist the condition optimization of MSPD, which comprehends the significance of the factors and their interactions with the least experimental runs. Under optimized MINs-MSPD-HPLC conditions, the detection limit of RhB was down to 0.14 mu g kg(-1) and excellent linearity over the wide range of 0.5-10000 mu g kg(-1) was attained. Furthermore, endogenous RhB was found in the tested food samples with relative standard deviations (RSDs) of <= 4.6%, and satisfactory recoveries were from 83.6 to 96.9%. The simple green MINs-MSPD method holds great potential for determination of trace RhB in complicated solid/semi-solid samples, showing rapidity, accuracy and reliability. |
| Funding Organization | Chinese Academy of Sciences President's International Fellowship Initiative [2019PC0050, 2020PC0083] ; National Natural Science Foundation of ChinaNational Natural Science Foundation of China [21876199, 21976099, 21976209] ; Key Research and Development Plan of Shandong Province of China [GG201709290055] ; Science and Technology Development Plan of Yantai City of China [2017ZH093] ; Taishan Scholar Project Special Funding [ts20190962] |
| Subtype | Article |
| Indexed By | SCI |
| Language | 英语 |
| WOS Keyword | POROUS CARBON MICROSPHERES ; SOLID-PHASE EXTRACTION ; HYDROTHERMAL SYNTHESIS ; SYNTHESIS STRATEGY ; RECOGNITION ; POLYMERS ; SURFACE ; BIOCOMPATIBILITY ; ENRICHMENT ; COMPOSITE |
| WOS ID | WOS:000528209200042 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.yic.ac.cn/handle/133337/25012 |
| Collection | 中科院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心 |
| Affiliation | 1.Chinese Acad Sci, Res Ctr Coastal Environm Engn & Technol, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China; 2.Univ Yasuj, Chem Dept, Yasuj 7591874831, Iran; 3.Qingdao Univ Technol, State Local Joint Engn Res Ctr Urban Sewage Treat, Sch Environm & Municipal Engn, Qingdao 266033, Peoples R China; 4.Qufu Normal Univ, Dept Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China; 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Arabi, Maryam,Ostovan, Abbas,Bagheri, Ahmad Reza,et al. Hydrophilic molecularly imprinted nanospheres for the extraction of rhodamine B followed by HPLC analysis: A green approach and hazardous waste elimination[J]. TALANTA,2020,215:120933. |
| APA | Arabi, Maryam.,Ostovan, Abbas.,Bagheri, Ahmad Reza.,Guo, Xiaotong.,Li, Jinhua.,...&Chen, Lingxin.(2020).Hydrophilic molecularly imprinted nanospheres for the extraction of rhodamine B followed by HPLC analysis: A green approach and hazardous waste elimination.TALANTA,215,120933. |
| MLA | Arabi, Maryam,et al."Hydrophilic molecularly imprinted nanospheres for the extraction of rhodamine B followed by HPLC analysis: A green approach and hazardous waste elimination".TALANTA 215(2020):120933. |
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| Hydrophilic molecula（2957KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Download | |
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