Soluble Molecularly Imprinted Nanorods for Homogeneous Molecular Recognition
Liang, Rongning1,2; Wang, Tiantian3; Zhang, Huan3; Yao, Ruiqing3; Qin, Wei1,2
2018-03-28
发表期刊FRONTIERS IN CHEMISTRY
ISSN2296-2646
卷号6
摘要Nowadays, it is still difficult for molecularly imprinted polymers (MIPs) to achieve homogeneous recognition since they cannot be easily dissolved in organic or aqueous phase. To address this issue, soluble molecularly imprinted nanorods have been synthesized by using soluble polyaniline doped with a functionalized organic protonic acid as the polymer matrix. By employing 1-naphthoic acid as a model, the proposed imprinted nanorods exhibit an excellent solubility and good homogeneous recognition ability. The imprinting factor for the soluble imprinted nanoroads is 6.8. The equilibrium dissociation constant and the apparent maximum number of the proposed imprinted nanorods are 248.5 mu M and 22.1 mu mol/g, respectively. We believe that such imprinted nanorods may provide an appealing substitute for natural receptors in homogeneous recognition related fields.
关键词Molecularly Imprinted Polymer Homogeneous Recognition Nanorods Soluble Polymer Polyanilines
DOI10.3389/fchem.2018.00081
项目资助者National Natural Science Foundation of China(21475148, 41576106) ; Strategic Priority Research Program of the Chinese Academy of Sciences(XDA11020702) ; Science and Technology Project of Yantai(2014ZH086) ; Youth Innovation Promotion Association of CAS(2014190) ; Taishan Scholar Program of Shandong Province(TS20081159)
收录类别SCI
关键词[WOS]CONDUCTING POLYANILINE ; POLYMERIZATION ; POLYMERS ; MICROSPHERES ; ANTIBODIES ; DENDRIMERS ; NANOGELS ; SENSORS ; SURFACE ; ENZYME
文章类型Article
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000428525500001
出版者FRONTIERS MEDIA SA
引用统计
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/24038
专题中科院海岸带环境过程与生态修复重点实验室
通讯作者Yao, Ruiqing; Qin, Wei
作者单位1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai, Peoples R China
2.Chinese Acad Sci, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai, Peoples R China
3.Northwest Univ, Sch Chem Engn, Xian, Shaanxi, Peoples R China
第一作者单位中国科学院烟台海岸带研究所
通讯作者单位中国科学院烟台海岸带研究所
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GB/T 7714
Liang, Rongning,Wang, Tiantian,Zhang, Huan,et al. Soluble Molecularly Imprinted Nanorods for Homogeneous Molecular Recognition[J]. FRONTIERS IN CHEMISTRY,2018,6.
APA Liang, Rongning,Wang, Tiantian,Zhang, Huan,Yao, Ruiqing,&Qin, Wei.(2018).Soluble Molecularly Imprinted Nanorods for Homogeneous Molecular Recognition.FRONTIERS IN CHEMISTRY,6.
MLA Liang, Rongning,et al."Soluble Molecularly Imprinted Nanorods for Homogeneous Molecular Recognition".FRONTIERS IN CHEMISTRY 6(2018).
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