Amphiphobic surface modification of electrospun nanofibrous membranes for anti-wetting performance in membrane distillation | |
An, Xiaochan1,3; Liu, Zhongyun1; Hu, Yunxia2![]() | |
发表期刊 | DESALINATION
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ISSN | 0011-9164 |
2018-04-15 | |
卷号 | 432页码:23-31 |
关键词 | Amphiphobic Surface Modification Membrane Distillation Anti-wetting Electrospinning Nanofibrous Membrane |
研究领域 | Engineering, Chemical ; Water Resources |
DOI | 10.1016/j.desal.2017.12.063 |
产权排序 | [An, Xiaochan; Liu, Zhongyun] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Res Ctr Coastal Environm Engn & Technol Shandong, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China; [Hu, Yunxia] Tianjin Polytech Univ, Sch Mat Sci & Engn, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China; [An, Xiaochan] Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
作者部门 | 海岸带环境工程技术研究与发展中心 |
英文摘要 | Membrane distillation (MD) works as a promising alternative of RO to desalinate hypersaline water owing to its unique advantages including high concentration brine tolerance, 100% theoretical solute rejection, and low operating pressure. Hydrophobic MD membranes face critical challenge to treat industrial wastewaters containing low surface tension substances because these substances led to membrane wetting with loss of membrane permeability and rejection. In this study, we report a simple and facile approach to fabricate amphiphobic polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) electrospun nanofibrous membranes with anti wetting property. 1H,1H,2H,2H-perfluorodecyltriethoxysilane (FAS) was used to fluorinate PVDF-HFP fibers and was then crosslinked to form a network upon dealcoholization under thermal treatment. The FAS-coated PVDF-HFP nanofibrous membranes exhibited great stable amphiphobicity with high contact angles against both water and oil, even challenged under critical conditions including boiling water, and strong base and acid etchings. Surface fluorination of PVDF-HFP nanofibrous membrane with the FAS coating did not sacrifice its permeate flux and salt rejection much. The fabricated amphiphobic nanofibrous membrane exhibited robust MD performance in the long-term operation and also in the presence of surfactant sodium dodecyl sulfate in the feed saline solution. |
文章类型 | Article |
资助机构 | National Natural Science Foundation of China(21476249) ; Key Science and Technology Program of Yantai City(2015ZH063) ; State Key Laboratory of Separation Membranes and Membrane Processes (Tianjin Polytechnic University)(M1-201503) |
收录类别 | SCI |
语种 | 英语 |
关键词[WOS] | SUPEROLEOPHOBIC SURFACES ; SUPERAMPHIPHOBIC FABRICS ; WASTE-WATER ; ROBUST ; COATINGS ; DESALINATION ; POLYMER ; ENVIRONMENT ; TECHNOLOGY ; SEPARATION |
研究领域[WOS] | Engineering ; Water Resources |
WOS记录号 | WOS:000428103300003 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/24026 |
专题 | 中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心 |
通讯作者 | Hu, Yunxia |
作者单位 | 1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Res Ctr Coastal Environm Engn & Technol Shandong, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China 2.Tianjin Polytech Univ, Sch Mat Sci & Engn, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | An, Xiaochan,Liu, Zhongyun,Hu, Yunxia. Amphiphobic surface modification of electrospun nanofibrous membranes for anti-wetting performance in membrane distillation[J]. DESALINATION,2018,432:23-31. |
APA | An, Xiaochan,Liu, Zhongyun,&Hu, Yunxia.(2018).Amphiphobic surface modification of electrospun nanofibrous membranes for anti-wetting performance in membrane distillation.DESALINATION,432,23-31. |
MLA | An, Xiaochan,et al."Amphiphobic surface modification of electrospun nanofibrous membranes for anti-wetting performance in membrane distillation".DESALINATION 432(2018):23-31. |
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