Colorimetric sensor for highly sensitive and selective detection of copper ion
Gao, Qi1,3; Ji, Ling2; Wang, Qiaoning3; Yin, Kun3; Li, Jinhua3; Chen, Lingxin3; Chen, Lingxin(Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res, 17 Chunhui Rd, Yantai 264003, Peoples R China)
2017-09-21
发表期刊ANALYTICAL METHODS
ISSN1759-9660
卷号9期号:35页码:5094-5100
产权排序第3完成单位
摘要The copper ion (Cu2+), as a type of essential element, plays important roles in various metabolic processes of organisms. However, an excessive intake of Cu2+ can induce a series of diseases, such as Alzheimer's disease, Menkes disease and Wilson's disease. Therefore, it is urgently needed to develop an analytical method to achieve a simple and sensitive detection of Cu2+. In this study, a colorimetric sensor for the detection of Cu2+ with a high sensitivity and selectivity has been developed. The design of the colorimetric sensor is based on the inhibiting effect of Cu2+ on the reaction of L-cysteine with our established probe Cy-NB. A significant color change could be directly observed by the naked eye as the concentration of Cu2+ increases. The as-prepared colorimetric sensor has a high sensitivity with a low detection limit of 8.6 nM, and a distinguishing recognition selectivity for Cu2+ over other possibly coexistent metal ions. Moreover, the sensor was successfully utilized for the analysis of tap water, seawater and biosamples, and high recoveries at two spiking levels of Cu2+ ranged from 102 to 114%. The results were consistent with those obtained by ICP-MS, indicating that the developed colorimetric sensor has great application potential as a simple highly sensitive and selective detection method for Cu2+.
DOI10.1039/c7ay01335c
项目资助者National Natural Science Foundation of China(21477160, 21575159)
URL查看原文
收录类别SCI
关键词[WOS]GOLD NANOPARTICLES ; EMISSION-SPECTROMETRY ; CYSTEINE DETECTION ; CU2+ ; RECOGNITION ; CHEMISTRY ; PRECONCENTRATION ; BIOSENSOR ; OXIDATION ; SILVER
文章类型Article
语种英语
WOS研究方向Chemistry ; Food Science & Technology ; Spectroscopy
WOS记录号WOS:000411529300003
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/23445
专题中科院海岸带环境过程与生态修复重点实验室
通讯作者Chen, Lingxin; Chen, Lingxin(Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res, 17 Chunhui Rd, Yantai 264003, Peoples R China)
作者单位1.China Agr Univ, Oceanog Inst, Dept Aquaculture, Yantai Res Inst, Yantai 264000, Peoples R China
2.State Ocean Adm, North China Sea Branch, Qingdao 266033, Peoples R China
3.Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res, 17 Chunhui Rd, Yantai 264003, Peoples R China
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Gao, Qi,Ji, Ling,Wang, Qiaoning,et al. Colorimetric sensor for highly sensitive and selective detection of copper ion[J]. ANALYTICAL METHODS,2017,9(35):5094-5100.
APA Gao, Qi.,Ji, Ling.,Wang, Qiaoning.,Yin, Kun.,Li, Jinhua.,...&Chen, Lingxin.(2017).Colorimetric sensor for highly sensitive and selective detection of copper ion.ANALYTICAL METHODS,9(35),5094-5100.
MLA Gao, Qi,et al."Colorimetric sensor for highly sensitive and selective detection of copper ion".ANALYTICAL METHODS 9.35(2017):5094-5100.
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