Pyrolysis temperature affects phosphorus transformation in biochar: Chemical fractionation and31P NMR analysis
Xu, Gang1; Zhang, You1,4; Shao, Hongbo1,2; Sun, Junna1,3; Shao, Hongbo (shaohongbochu@126.com)
发表期刊Science of the Total Environment
ISSN0048-9697
2016-11-01
卷号569-570页码:65-72
关键词Cracking (Chemical)-agricultural Wastes Chemical Analysis Crops Decay (Organic) Feedstocks Phosphate Minerals Phosphorus Pyrolysis Water Treatment Bio Chars Chemical Fractionation Hedley Fraction Phosphorus Transformations Pyrolysis Temperature Pyrophosphate Salt Soils Sequential Fractionation
DOI10.1016/j.scitotenv.2016.06.081
产权排序(1) Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai; 264003, China; (2) Institute of Agro-biotechnology, Jiangsu Academy of Agricultural Sciences, Nanjing, China; (3) College of Life Science, Ludong University, Yantai; 264005, China; (4) University of Chinese Academy of Sciences, Beijing; 100049, China
作者部门海岸带生物学与生物资源利用所重点实验室
英文摘要Phosphorus (P) recycling or reuse by pyrolyzing crop residue has recently elicited increased research interest. However, the effects of feedstock and pyrolysis conditions on P species have not been fully understood. Such knowledge is important in identifying the agronomic and environmental uses of biochar. Residues of three main Chinese agricultural crops and the biochars (produced at 300 °C–600 °C) derived from these crops were used to determine P transformations during pyrolysis. Hedley sequential fractionation and31P NMR analyses were used in the investigation. Our results showed that P transformation in biochar was significantly affected by pyrolysis temperature regardless of feedstock (Wheat straw, maize straw and peanut husk). Pyrolysis treatment transformed water soluble P into a labile (NaHCO3-Pi) or semi-labile pool (NaOH-Pi) and into a stable pool (Dil. HCl P and residual-P). At the same time, organic P was transformed into inorganic P fractions which was identified by the rapid decomposition of organic P detected with solution31P NMR. The P transformation during pyrolysis process suggested more stable P was formed at a higher pyrolysis temperature. This result was also evidenced by the presence of less soluble or stable P species, such as such as poly-P, crandallite (CaAl3(OH)5(PO4)2) and Wavellite (Al3(OH)3(PO4)2·5H2O), as detected by solid-state31P NMR in biochars formed at a higher pyrolysis temperature. Furthermore, a significant proportion of less soluble pyrophosphate was identified by solution (2%–35%) and solid-state (8%–53%)31P NMR, which was also responsible for the stable P forms at higher pyrolysis temperature although their solubility or stability requires further investigation. Results suggested that a relatively lower pyrolysis temperature retains P availability regardless of feedstock during pyrolysis process.
文章类型Journal article
资助机构National Natural Science Foundation of China 41573120 41001137 ; National Basic Research Program of China 2013CB430403 ; Shuangchuang Talent Plan of Jiangsu Province ; JiangsuAgricultural Science and Technology Innovation Fund CX(15)1005
语种英语
关键词[WOS]NUCLEAR-MAGNETIC-RESONANCE; SOIL-PHOSPHORUS; ORGANIC-CARBON; MANURE; AVAILABILITY; SPECIATION; NITROGEN; COMPOST; RELEASE; IMPACT
研究领域[WOS]Water Treatment Techniques ; Minerals ; Chemical Reactions ; Chemical Products Generally ; Agricultural Products ; Agricultural Wastes
WOS记录号WOS:23
引用统计
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/17503
专题海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室
通讯作者Shao, Hongbo (shaohongbochu@126.com)
作者单位1.Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences
2.Institute of Agro-biotechnology, Jiangsu Academy of Agricultural Sciences
3.College of Life Science, Ludong University
4.University of Chinese Academy of Sciences
推荐引用方式
GB/T 7714
Xu, Gang,Zhang, You,Shao, Hongbo,et al. Pyrolysis temperature affects phosphorus transformation in biochar: Chemical fractionation and31P NMR analysis[J]. Science of the Total Environment,2016,569-570:65-72.
APA Xu, Gang,Zhang, You,Shao, Hongbo,Sun, Junna,&Shao, Hongbo .(2016).Pyrolysis temperature affects phosphorus transformation in biochar: Chemical fractionation and31P NMR analysis.Science of the Total Environment,569-570,65-72.
MLA Xu, Gang,et al."Pyrolysis temperature affects phosphorus transformation in biochar: Chemical fractionation and31P NMR analysis".Science of the Total Environment 569-570(2016):65-72.
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