In Situ ATR-FTIR Investigation of Photodegradation of 3,4-Dihydroxybenzoic Acid on TiO2
其他题名In Situ ATR-FTIR Investigation of Photodegradation of 3,4-Dihydroxybenzoic Acid on TiO2
Hu, Xuefeng1; Burgi, Thomas2; Hu, XF (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China. Email:xfhu@yic.ac.cn
发表期刊CATALYSIS LETTERS
ISSN1011-372X
2016-11-01
卷号146期号:11页码:2215-2220
关键词In Situ Spectroscopy Photocatalysis Attenuated Total Reflection Tio2 3 4-dihydroxybenzoic Acid
DOI10.1007/s10562-016-1838-y
产权排序[Hu, Xuefeng] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China; [Burgi, Thomas] Univ Geneva, Dept Chim Phys, Quai Ernest Ansermet 30, CH-1211 Geneva 4, Switzerland
作者部门中科院海岸带环境过程与生态修复重点实验室
英文摘要The catalytic photo-oxidation of 3,4-dihydroxybenzoic acid on TiO2 has been studied by in situ ATR-FTIR in flowing water and in flowing wet air/nitrogen gas. In flowing water it was difficult to observe photodegradation intermediates despite photocatalytic action during UV illumination. In the flowing wet air/nitrogen system carboxylic acids and carbonates were observed. It was shown that water plays an important role in the formation of oxidation active species. Oxygen shows a prominent role for carboxylic acid degradation, but the photogenerated hole plays the important role for the 3,4-dihydroxybenzoic acid ring cleavage.
文章类型Article
资助机构National Science Foundation of China(41076040 ; 41230858)
收录类别SCI
语种英语
关键词[WOS]PHOTOCATALYTIC DEGRADATION ; INFRARED-SPECTROSCOPY ; TITANIUM-DIOXIDE ; IR SPECTROSCOPY ; WATER ; ADSORPTION ; COMPLEXES ; MECHANISM ; KINETICS ; CATECHOL
研究领域[WOS]Chemistry
WOS记录号WOS:000387325300001
引用统计
被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/17487
专题中国科学院海岸带环境过程与生态修复重点实验室
通讯作者Hu, XF (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China. Email:xfhu@yic.ac.cn
作者单位1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China
2.Univ Geneva, Dept Chim Phys, Quai Ernest Ansermet 30, CH-1211 Geneva 4, Switzerland
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GB/T 7714
Hu, Xuefeng,Burgi, Thomas,Hu, XF . In Situ ATR-FTIR Investigation of Photodegradation of 3,4-Dihydroxybenzoic Acid on TiO2[J]. CATALYSIS LETTERS,2016,146(11):2215-2220.
APA Hu, Xuefeng,Burgi, Thomas,&Hu, XF .(2016).In Situ ATR-FTIR Investigation of Photodegradation of 3,4-Dihydroxybenzoic Acid on TiO2.CATALYSIS LETTERS,146(11),2215-2220.
MLA Hu, Xuefeng,et al."In Situ ATR-FTIR Investigation of Photodegradation of 3,4-Dihydroxybenzoic Acid on TiO2".CATALYSIS LETTERS 146.11(2016):2215-2220.
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