Graphene oxide-assisted synthesis of bismuth nanosheets for catalytic stripping voltammetric determination of iron in coastal waters
Hu, XP; Pan, DW; Lin, MY; Han, HT; Li, F; Pan, DW (reprint author), Chinese Acad Sci, Shandong Prov Key Lab Coastal Environm Proc, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China.; Pan, DW (reprint author), Univ Liverpool, Sch Environm Sci, Dept Earth Ocean & Ecol Sci, Liverpool L69 3GP, Merseyside, England. dwpan@yic.ac.cn
发表期刊MICROCHIMICA ACTA
ISSN0026-3672
2016-02-01
卷号183期号:2页码:855-861
关键词Differential Pulse Voltammetry Catalytic Current Amplification Scanning Electron Microscopy Energy Dispersive X-ray Spectroscopy
DOI10.1007/s00604-015-1733-z
产权排序[Hu, Xueping; Pan, Dawei; Lin, Mingyue; Han, Haitao] Chinese Acad Sci, Shandong Prov Key Lab Coastal Environm Proc, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China; [Pan, Dawei] Univ Liverpool, Sch Environm Sci, Dept Earth Ocean & Ecol Sci, Liverpool L69 3GP, Merseyside, England; [Hu, Xueping; Lin, Mingyue] Univ Chinese Acad Sci, Beijing 100049, Peoples R China; [Li, Fei] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Shandong, Peoples R China
作者部门中科院海岸带环境过程与生态修复重点实验室
英文摘要The article describes the synthesis of bismuth nanosheets (BiNSs) in the presence of a small quantity of graphene oxide (GO) which is helpful for the formation of two-dimensional BiNSs and improves dispersity. The material, when placed on a glassy carbon electrode (GCE), is shown to enable catalytic stripping voltammetric determination of total dissolved iron without the need for adding a complexing agent. The average thickness and length of the BiNSs are 3 to 4 nm and 100 to 200 nm, respectively. The unique nanostructure of the BiNSs, the ability of Bi to form alloys with metal, and the current amplification of the catalytic system make the modified GCE an excellent choice for electrochemical determination of Fe(III). Under the optimal conditions, the electrode has a linear response to Fe(III) in the 0.01 to 20 mu M concentrations range, with a lower detection limit of 2.3 nM. The electrode was successfully applied to the sensitive determination of Fe(III) in coastal waters.
文章类型Article
资助机构National Natural Science Foundation of China(41276093) ; Youth Innovation Promotion Association(2011170) ; Outstanding Young Scientists of CAS
收录类别SCI
语种英语
关键词[WOS]GLASSY-CARBON ELECTRODE ; FILM ELECTRODE ; GOLD NANOPARTICLES ; PASTE ELECTRODE ; HEAVY-METALS ; TRACE IRON ; IRON(III) ; SEAWATER ; ACID ; PHYTOPLANKTON
研究领域[WOS]Chemistry
WOS记录号WOS:000370176500042
引用统计
被引频次:53[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/10860
专题中国科学院海岸带环境过程与生态修复重点实验室
通讯作者Pan, DW (reprint author), Chinese Acad Sci, Shandong Prov Key Lab Coastal Environm Proc, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China.; Pan, DW (reprint author), Univ Liverpool, Sch Environm Sci, Dept Earth Ocean & Ecol Sci, Liverpool L69 3GP, Merseyside, England. dwpan@yic.ac.cn
作者单位1.Chinese Acad Sci, Shandong Prov Key Lab Coastal Environm Proc, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Environm Proc & Ecol Remediat
2.Univ Liverpool, Sch Environm Sci, Dept Earth Ocean & Ecol Sci
3.Univ Chinese Acad Sci
4.Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci
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Hu, XP,Pan, DW,Lin, MY,et al. Graphene oxide-assisted synthesis of bismuth nanosheets for catalytic stripping voltammetric determination of iron in coastal waters[J]. MICROCHIMICA ACTA,2016,183(2):855-861.
APA Hu, XP.,Pan, DW.,Lin, MY.,Han, HT.,Li, F.,...&Pan, DW .(2016).Graphene oxide-assisted synthesis of bismuth nanosheets for catalytic stripping voltammetric determination of iron in coastal waters.MICROCHIMICA ACTA,183(2),855-861.
MLA Hu, XP,et al."Graphene oxide-assisted synthesis of bismuth nanosheets for catalytic stripping voltammetric determination of iron in coastal waters".MICROCHIMICA ACTA 183.2(2016):855-861.
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