Water: the most effective solvent for liquid-phase hydrodechlorination of chlorophenols over Raney Ni catalyst
Ma, Xuanxuan; Liu, Ying; Li, Xiaoqiang; Xu, Jinguang; Gu, Guodong; Xia, Chuanhai; Liu, Y (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Biol Resources Utilizat, Yantai 264003, Peoples R China. yliu@yic.ac.cn; chxia@yic.ac.cn
发表期刊APPLIED CATALYSIS B-ENVIRONMENTAL
ISSN0926-3373
2015-04
卷号165页码:351-359
关键词Raney Ni Chlorophenols Hydrodechlorination (Hdc) Water Solvent Effects
DOI10.1016/j.apcatb.2014.10.035
产权排序[Ma, Xuanxuan; Liu, Ying; Xia, Chuanhai] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Biol Resources Utilizat, Yantai 264003, Peoples R China; [Ma, Xuanxuan] Univ Chinese Acad Sci, Beijing 100049, Peoples R China; [Li, Xiaoqiang; Xu, Jinguang] Yantai Univ, Yantai 264005, Peoples R China; [Gu, Guodong] Alliance Pharma Inc, Malvern, PA 19355 USA
作者部门海岸带生物学与生物资源利用所重点实验室
英文摘要Catalytic hydrodechlorination (HDC) has proved to be an efficient approach to dispose chlorinated organic compounds (COCs). The influence of solvent on the HOC of chlorophenols with H-2 over Raney Ni catalyst was investigated. We found that protic solvents, especially water, significantly accelerated liquid-phase HOC that was sluggish in aprotic solvents. Among the selected solvents, water was the most effective solvent for liquid-phase HDC over Raney Ni catalyst. To study the mechanism for the rate acceleration in the HOC that was promoted by protic solvents, catalysts were characterized by SEM, EDX, and XRD techniques. It was found that solvent could affect surface composition and surface micro-topography of Raney Ni catalyst. On the basis of these studies, an effective and practical reaction system was developed to dispose chlorophenols over Raney Ni catalyst; a broad range of chlorophenols were efficiently hydrodechlorinated in aqueous solutions under mild conditions, and the catalyst could be reused at least five times without any loss of catalytic activity. (C) 2014 Elsevier B.V. All rights reserved.
文章类型期刊论文
资助机构Chemistry ; Engineering
收录类别SCI
语种英语
关键词[WOS]PD/FE BIMETALLIC NANOPARTICLES ; MILD CONDITIONS ; ORGANIC-SYNTHESIS ; PILLARED CLAYS ; MIXED-SOLVENTS ; PRACTICAL USE ; RH CATALYSTS ; WASTE-WATER ; ON-WATER ; PD
研究领域[WOS]National Science Foundation of China [21377162, 21007088] ; Knowledge Innovation Program of Chinese Academy of Sciences [KZCX2-EW-206]
WOS记录号WOS:000347584200039
引用统计
被引频次:50[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/8508
专题海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室
通讯作者Liu, Y (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Biol Resources Utilizat, Yantai 264003, Peoples R China. yliu@yic.ac.cn; chxia@yic.ac.cn
推荐引用方式
GB/T 7714
Ma, Xuanxuan,Liu, Ying,Li, Xiaoqiang,et al. Water: the most effective solvent for liquid-phase hydrodechlorination of chlorophenols over Raney Ni catalyst[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2015,165:351-359.
APA Ma, Xuanxuan.,Liu, Ying.,Li, Xiaoqiang.,Xu, Jinguang.,Gu, Guodong.,...&chxia@yic.ac.cn.(2015).Water: the most effective solvent for liquid-phase hydrodechlorination of chlorophenols over Raney Ni catalyst.APPLIED CATALYSIS B-ENVIRONMENTAL,165,351-359.
MLA Ma, Xuanxuan,et al."Water: the most effective solvent for liquid-phase hydrodechlorination of chlorophenols over Raney Ni catalyst".APPLIED CATALYSIS B-ENVIRONMENTAL 165(2015):351-359.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
Water-promoted catal(2032KB) 开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Ma, Xuanxuan]的文章
[Liu, Ying]的文章
[Li, Xiaoqiang]的文章
百度学术
百度学术中相似的文章
[Ma, Xuanxuan]的文章
[Liu, Ying]的文章
[Li, Xiaoqiang]的文章
必应学术
必应学术中相似的文章
[Ma, Xuanxuan]的文章
[Liu, Ying]的文章
[Li, Xiaoqiang]的文章
相关权益政策
暂无数据
收藏/分享
文件名: Water-promoted catalytic hydrodechlorination of transformer oil-contained PCBs in liquid system under mild conditions.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。