Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
| Adsorption and desorption characteristics of diphenylarsenicals in two contrasting soils | |
Wang, Anan1,2; Li, Shixin1,2; Teng, Ying1; Liu, Wuxin1; Wu, Longhua1; Zhang, Haibo1 ; Huang, Yujuan1; Luo, Yongming1,3; Christie, Peter4; Luo, YM (reprint author), Chinese Acad Sci, Inst Soil Sci, Key Lab Soil Environm & Pollut Remediat, Nanjing 210008, Jiangsu, Peoples R China. ananwang@issas.ac.cn; ymluo@yic.ac.cn
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| 发表期刊 | JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA
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| ISSN | 1001-0742 |
| 2013-06-01 | |
| 卷号 | 25期号:6页码:1172-1179 |
| 关键词 | Diphenylarsinic Acid Adsorption And Desorption Chemical Weapons Residual Soil Contamination |
| 产权排序 | [Wang, Anan; Li, Shixin; Teng, Ying; Liu, Wuxin; Wu, Longhua; Zhang, Haibo; Huang, Yujuan; Luo, Yongming] Chinese Acad Sci, Inst Soil Sci, Key Lab Soil Environm & Pollut Remediat, Nanjing 210008, Jiangsu, Peoples R China; [Wang, Anan; Li, Shixin] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China; [Luo, Yongming] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China; [Christie, Peter] Agri Food & Biosci Inst, Agri Environm Branch, Belfast BT9 5PX, Antrim, North Ireland |
| 英文摘要 | Diphenylarsinic acid (DPAA) is formed during the leakage of aromatic arsenic chemical weapons in soils, is persistent in nature, and results in arsenic contamination in the field. The adsorption and desorption characteristics of DPAA were investigated in two typical Chinese soils, an Acrisol (a variable-charge soil) and a Phaeozem (a constant-charge soil). Their thermodynamics and some of the factors influencing them (i.e., initial pH value, ionic strength and phosphate) were also evaluated using the batch method in order to understand the environmental fate of DPAA in soils. The results indicate that Acrisol had a stronger adsorption capacity for DPAA than Phaeozem. Soil DPAA adsorption was a spontaneous and endothermic process and the amount of DPAA adsorbed was affected significantly by variation in soil pH and phosphate. In contrast, soil organic matter and ionic strength had no significant effect on adsorption. This suggests that DPAA adsorption may be due to specific adsorption on soil mineral surfaces. Therefore, monitoring the fate of DPAA in soils is recommended in areas contaminated by leakage from chemical weapons.; Diphenylarsinic acid (DPAA) is formed during the leakage of aromatic arsenic chemical weapons in soils, is persistent in nature, and results in arsenic contamination in the field. The adsorption and desorption characteristics of DPAA were investigated in two typical Chinese soils, an Acrisol (a variable-charge soil) and a Phaeozem (a constant-charge soil). Their thermodynamics and some of the factors influencing them (i.e., initial pH value, ionic strength and phosphate) were also evaluated using the batch method in order to understand the environmental fate of DPAA in soils. The results indicate that Acrisol had a stronger adsorption capacity for DPAA than Phaeozem. Soil DPAA adsorption was a spontaneous and endothermic process and the amount of DPAA adsorbed was affected significantly by variation in soil pH and phosphate. In contrast, soil organic matter and ionic strength had no significant effect on adsorption. This suggests that DPAA adsorption may be due to specific adsorption on soil mineral surfaces. Therefore, monitoring the fate of DPAA in soils is recommended in areas contaminated by leakage from chemical weapons. |
| 文章类型 | Article |
| 资助机构 | National Natural Science Foundation of China [41171248, 40810180]; Ministry of Environmental Protection Special Funds for Scientific Research on Public Causes [2010467016] |
| 收录类别 | SCI |
| 语种 | 英语 |
| 关键词[WOS] | CHEMICAL WARFARE AGENTS ; ORGANIC-MATTER ; IONIC-STRENGTH ; PHENYLARSENIC COMPOUNDS ; AGRICULTURAL SOILS ; ARSENIC ADSORPTION ; AQUEOUS-SOLUTIONS ; OXIDE MINERALS ; IRON-OXIDES ; SORPTION |
| 研究领域[WOS] | Environmental Sciences & Ecology |
| WOS记录号 | WOS:000320749900016 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.yic.ac.cn/handle/133337/6987 |
| 专题 | 中国科学院海岸带环境过程与生态修复重点实验室 |
| 通讯作者 | Luo, YM (reprint author), Chinese Acad Sci, Inst Soil Sci, Key Lab Soil Environm & Pollut Remediat, Nanjing 210008, Jiangsu, Peoples R China. ananwang@issas.ac.cn; ymluo@yic.ac.cn |
| 作者单位 | 1.Chinese Acad Sci, Inst Soil Sci, Key Lab Soil Environm & Pollut Remediat, Nanjing 210008, Jiangsu, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China 4.Agri Food & Biosci Inst, Agri Environm Branch, Belfast BT9 5PX, Antrim, North Ireland |
| 推荐引用方式 GB/T 7714 | Wang, Anan,Li, Shixin,Teng, Ying,et al. Adsorption and desorption characteristics of diphenylarsenicals in two contrasting soils[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2013,25(6):1172-1179. |
| APA | Wang, Anan.,Li, Shixin.,Teng, Ying.,Liu, Wuxin.,Wu, Longhua.,...&ymluo@yic.ac.cn.(2013).Adsorption and desorption characteristics of diphenylarsenicals in two contrasting soils.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,25(6),1172-1179. |
| MLA | Wang, Anan,et al."Adsorption and desorption characteristics of diphenylarsenicals in two contrasting soils".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 25.6(2013):1172-1179. |
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