Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
Photochlorination of aniline in Fe3+-containing saline water under simulated solar light irradiation | |
Wu, Lei1,2; Hu, Xuefeng1 | |
发表期刊 | ENVIRONMENTAL CHEMISTRY |
ISSN | 1448-2517 |
2012 | |
卷号 | 9期号:6页码:558-563 |
关键词 | Chloroanilines |
产权排序 | [Wu, Lei; Hu, Xuefeng] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China; [Wu, Lei] Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
通讯作者 | Hu, XF (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China.,xfhu@yic.ac.cn |
作者部门 | 中科院海岸带环境过程与生态修复重点实验室 |
英文摘要 | Photochlorination of aniline was observed in aqueous solutions containing dissolved Fe-III and chloride ions under simulated solar light irradiation. Effects of O-2, Cl-, Fe3+ and pH on the formation of chloroanilines (CAs) were investigated. para-chloroaniline (4CA) was identified as the main chlorinated product. The formation of 4CA is enhanced with increased concentrations of Cl- or Fe3+, and decreased pH, whereas oxygen plays a negligible role in the process. The results indicate that, Cl-center dot is formed mainly by the photodissociation of FeCl2+-FeCl2+ complexes, and reacts with Cl- to produce Cl-2(center dot-). Aniline is then oxidised by Cl-2(center dot-) into an anilino radical cation, which further reacts with Cl-2(center dot-) to generate CAs. The photochlorination of aniline in natural seawater was also observed. Other phototransformation products of aniline were detected and a transformation pathway was proposed. This work provides evidence for the photochemical chlorination path of aniline-based aromatic amines in aqueous solutions.; Photochlorination of aniline was observed in aqueous solutions containing dissolved Fe-III and chloride ions under simulated solar light irradiation. Effects of O-2, Cl-, Fe3+ and pH on the formation of chloroanilines (CAs) were investigated. para-chloroaniline (4CA) was identified as the main chlorinated product. The formation of 4CA is enhanced with increased concentrations of Cl- or Fe3+, and decreased pH, whereas oxygen plays a negligible role in the process. The results indicate that, Cl-center dot is formed mainly by the photodissociation of FeCl2+-FeCl2+ complexes, and reacts with Cl- to produce Cl-2(center dot-). Aniline is then oxidised by Cl-2(center dot-) into an anilino radical cation, which further reacts with Cl-2(center dot-) to generate CAs. The photochlorination of aniline in natural seawater was also observed. Other phototransformation products of aniline were detected and a transformation pathway was proposed. This work provides evidence for the photochemical chlorination path of aniline-based aromatic amines in aqueous solutions. |
文章类型 | Article |
资助机构 | National Natural Science Foundation of China [41076040, 20807036] |
收录类别 | SCI |
语种 | 英语 |
关键词[WOS] | AQUEOUS-SOLUTION ; ORGANIC-COMPOUNDS ; FENTON PROCESSES ; ELECTRO-FENTON ; BISPHENOL-A ; DEGRADATION ; OXIDATION ; DERIVATIVES ; MECHANISM ; KINETICS |
研究领域[WOS] | Chemistry ; Environmental Sciences & Ecology |
WOS记录号 | WOS:000314458800008 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/6030 |
专题 | 中国科学院海岸带环境过程与生态修复重点实验室 |
作者单位 | 1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Wu, Lei,Hu, Xuefeng. Photochlorination of aniline in Fe3+-containing saline water under simulated solar light irradiation[J]. ENVIRONMENTAL CHEMISTRY,2012,9(6):558-563. |
APA | Wu, Lei,&Hu, Xuefeng.(2012).Photochlorination of aniline in Fe3+-containing saline water under simulated solar light irradiation.ENVIRONMENTAL CHEMISTRY,9(6),558-563. |
MLA | Wu, Lei,et al."Photochlorination of aniline in Fe3+-containing saline water under simulated solar light irradiation".ENVIRONMENTAL CHEMISTRY 9.6(2012):558-563. |
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