Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
| Currently used pesticides, hexachlorobenzene and hexachlorocyclohexanes in the air and seawater of the German Bight (North Sea) | |
Zhong, Guangcai1,2,3; Xie, Zhiyong1; Moeller, Axel1; Halsall, Crispin4; Caba, Armando1; Sturm, Renate1; Tang, Jianhui2 ; Zhang, Gan5; Ebinghaus, Ralf1
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| 发表期刊 | ENVIRONMENTAL CHEMISTRY
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| ISSN | 1448-2517 |
| 2012 | |
| 卷号 | 9期号:4页码:405-414 |
| 关键词 | Persistent Organic Pollutants Western United-states Water Gas-exchange Organochlorine Pesticides Atmospheric Concentrations Polychlorinated-biphenyls Chesapeake Bay Atlantic-ocean Arctic-ocean Dacthal |
| 产权排序 | [Zhong, Guangcai; Xie, Zhiyong; Moeller, Axel; Caba, Armando; Sturm, Renate; Ebinghaus, Ralf] Helmholtz Zentrum Geesthacht, Ctr Mat & Coastal Res, Inst Coastal Res, D-21502 Geesthacht, Germany; [Zhong, Guangcai; Tang, Jianhui] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Zone Environm Proc, Yantai 264003, Peoples R China; [Zhong, Guangcai] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China; [Halsall, Crispin] Univ Lancaster, Lancaster Environm Ctr, Ctr Chem Management, Lancaster LA1 4YQ, England; [Zhang, Gan] Chinese Acad Sci, Guangzhou Geochem Inst, Guangzhou 510640, Guangdong, Peoples R China |
| 通讯作者 | Zhong, GC (reprint author), Helmholtz Zentrum Geesthacht, Ctr Mat & Coastal Res, Inst Coastal Res, Max Planck Str 1, D-21502 Geesthacht, Germany.,guangcai.zhong@hzg.de |
| 作者部门 | 中科院海岸带环境过程与生态修复重点实验室 |
| 英文摘要 | Surface seawater and air samples collected from the German Bight (North Sea) in March, May and July 2010 were analysed for hexachlorobenzene (HCB) and hexachlorocyclohexanes (HCHs), five currently used pesticides (CUPs) (trifluralin, endosulfan, chlorpyrifos, dacthal and quintozene) and pentachloroanisole (metabolite). Volatilisation from local surfaces was considered to be the main source of these chemicals to the air (excluding trifluralin). Long-range transport from Western Europe partly contributed to the higher air concentrations observed in July whereas riverine input was the main source for HCHs and pentachloroanisole in seawater in March. Air-sea gas exchange of HCB and alpha-HCH in the German Bight was found to be near equilibrium, probably reflecting the past use of these chemicals, their wide dispersal in the environment and lack of contemporary use. Deposition of target compounds from the air to seawater was observed to be much higher in July compared with depositional fluxes for March and May, except for chlorpyrifos (with volatilisation fluxes in all sampling periods: similar to 25 ngm (2) day (1)). Concentrations of trifluralin in seawater appear to have decreased since its restriction of use in European Union member states, with net volatilisation from seawater observed in March (flux: 6.3 +/- 7.2 ng m(-2) day(-1)). With the exception of chlorpyrifos, our results indicate that volatilisation from local sources combined with long-range transport from Western Europe and subsequent deposition are important pathways for these compounds to German Bight seawater during summer periods.; Surface seawater and air samples collected from the German Bight (North Sea) in March, May and July 2010 were analysed for hexachlorobenzene (HCB) and hexachlorocyclohexanes (HCHs), five currently used pesticides (CUPs) (trifluralin, endosulfan, chlorpyrifos, dacthal and quintozene) and pentachloroanisole (metabolite). Volatilisation from local surfaces was considered to be the main source of these chemicals to the air (excluding trifluralin). Long-range transport from Western Europe partly contributed to the higher air concentrations observed in July whereas riverine input was the main source for HCHs and pentachloroanisole in seawater in March. Air-sea gas exchange of HCB and alpha-HCH in the German Bight was found to be near equilibrium, probably reflecting the past use of these chemicals, their wide dispersal in the environment and lack of contemporary use. Deposition of target compounds from the air to seawater was observed to be much higher in July compared with depositional fluxes for March and May, except for chlorpyrifos (with volatilisation fluxes in all sampling periods: similar to 25 ngm (2) day (1)). Concentrations of trifluralin in seawater appear to have decreased since its restriction of use in European Union member states, with net volatilisation from seawater observed in March (flux: 6.3 +/- 7.2 ng m(-2) day(-1)). With the exception of chlorpyrifos, our results indicate that volatilisation from local sources combined with long-range transport from Western Europe and subsequent deposition are important pathways for these compounds to German Bight seawater during summer periods. |
| 文章类型 | Article |
| 收录类别 | SCI |
| 语种 | 英语 |
| 关键词[WOS] | PERSISTENT ORGANIC POLLUTANTS ; WESTERN UNITED-STATES ; WATER GAS-EXCHANGE ; ORGANOCHLORINE PESTICIDES ; ATMOSPHERIC CONCENTRATIONS ; POLYCHLORINATED-BIPHENYLS ; CHESAPEAKE BAY ; ATLANTIC-OCEAN ; ARCTIC-OCEAN ; DACTHAL |
| 研究领域[WOS] | Chemistry ; Environmental Sciences & Ecology |
| WOS记录号 | WOS:000307669700007 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.yic.ac.cn/handle/133337/5974 |
| 专题 | 中国科学院海岸带环境过程与生态修复重点实验室 |
| 作者单位 | 1.Helmholtz Zentrum Geesthacht, Ctr Mat & Coastal Res, Inst Coastal Res, D-21502 Geesthacht, Germany 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Zone Environm Proc, Yantai 264003, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 4.Univ Lancaster, Lancaster Environm Ctr, Ctr Chem Management, Lancaster LA1 4YQ, England 5.Chinese Acad Sci, Guangzhou Geochem Inst, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhong, Guangcai,Xie, Zhiyong,Moeller, Axel,et al. Currently used pesticides, hexachlorobenzene and hexachlorocyclohexanes in the air and seawater of the German Bight (North Sea)[J]. ENVIRONMENTAL CHEMISTRY,2012,9(4):405-414. |
| APA | Zhong, Guangcai.,Xie, Zhiyong.,Moeller, Axel.,Halsall, Crispin.,Caba, Armando.,...&Ebinghaus, Ralf.(2012).Currently used pesticides, hexachlorobenzene and hexachlorocyclohexanes in the air and seawater of the German Bight (North Sea).ENVIRONMENTAL CHEMISTRY,9(4),405-414. |
| MLA | Zhong, Guangcai,et al."Currently used pesticides, hexachlorobenzene and hexachlorocyclohexanes in the air and seawater of the German Bight (North Sea)".ENVIRONMENTAL CHEMISTRY 9.4(2012):405-414. |
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