Evaluating the bioenergy potential of kitchen wastes fermentation residues through pyrolysis kinetics, thermodynamics and Py-GC/MS analysis technique

doi:10.1007/s10973-022-11711-y

	Evaluating the bioenergy potential of kitchen wastes fermentation residues through pyrolysis kinetics, thermodynamics and Py-GC/MS analysis technique
	Zhao, Hui 1,2; Zhang, Huirong 1; Sun, Mingze 1; Liu, Bo 1; Chen, Wenjie 1; Dang, Chuanyu 1,2; Zhong, Hui 1,3; Jiang, Jinju 1,5; Qin, Song1,4 ; Han, Zuozhen 1; Yan, Huaxiao 1,2
发表期刊	JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN	1388-6150
	2022-11-08
页码	16
关键词	Kitchen wastes fermentation residues Thermogravimetric analysis Thermodynamic analysis Kinetics Non-isothermal Pyrolysis-GC MS
DOI	10.1007/s10973-022-11711-y
通讯作者	Zhao, Hui(zhsdust@126.com) ; Yan, Huaxiao(skd992042@sdust.edu.cn)
英文摘要	Pyrolysis non-isothermal kinetics, thermodynamics and products compositional characteristics of kitchen wastes fermentation residues (KWFR) were investigated to explore the bioenergy potential by thermogravimetric analysis and pyrolysis gas chromatography mass spectrometry (Py-GC/MS) methods. The results showed that pyrolysis process can be divided into four common stages. The kinetics results deduced from FWO, KAS and Popescu methods showed that reaction activation energy (E) was 170.56, 168.98 and 172.10 kJ mol(-1) and pre-exponential factor (A) was 1.22E + 17, 5.04E + 10 and 1.80E + 15 min(-1), respectively, while the optimal mechanism function was G(alpha) = [1 - (1 - alpha)(1/3)](2)(n = 2). The calculated thermodynamic parameters included Delta H (163.77-166.90 kJ mol(-1)), Delta S (- 62.25-61.28 J mol(-1) K-1) and Delta G (145.41-184.02 kJ mol(-1)). The Py-GC/MS results showed mainly produced nitrogen-containing compounds, acidic alcohol compounds, aldehydes, ketones, esters, benzenes and hydrocarbons. This study highlights KWFR can be considered as an attractive feedstock for bioenergy and bio-based chemicals and meanwhile may help to solve the problem of kitchen wastes digestion tailings.
资助机构	National Natural Science Foundation of China ; Shandong Key Research and Development Program Major Science and technology innovation engineering projects ; Natural Science Foundation of Shandong Province
收录类别	SCI
语种	英语
关键词[WOS]	TG-FTIR ; PRODUCT DISTRIBUTION ; GAS CHROMATOGRAPHY ; CO-PYROLYSIS ; HEATING RATE ; SOLID-WASTE ; BIOMASS ; BEHAVIOR ; STALK ; MS
研究领域[WOS]	Thermodynamics ; Chemistry
WOS记录号	WOS:000880271000007
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/32015
专题	海岸带生物学与生物资源利用重点实验室海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室
通讯作者	Zhao, Hui; Yan, Huaxiao
作者单位	1.Shandong Univ Sci & Technol, Coll Chem & Biol Engn, Shandong Innovat Ctr Nongrain Ethanol Biorefinery, Dept Bioengn, Qingdao 266590, Peoples R China 2.Shandong Hongda Biol Grp Co Ltd, Shandong Innovat Ctr Nongrain Ethanol Biorefinery, Linyi 276400, Shandong, Peoples R China 3.Qingdao Tianren Environm Co Ltd, Natl Engn Technol Ctr Environm Protect Livestock, Qingdao 266101, Peoples R China 4.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Shandong, Peoples R China 5.Qingdao Brightmoon Seaweed Grp Co Ltd, State Key Lab Bioact Seaweed Subst, Qingdao 266400, Shandong, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Hui,Zhang, Huirong,Sun, Mingze,et al. Evaluating the bioenergy potential of kitchen wastes fermentation residues through pyrolysis kinetics, thermodynamics and Py-GC/MS analysis technique[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2022:16.
APA	Zhao, Hui.,Zhang, Huirong.,Sun, Mingze.,Liu, Bo.,Chen, Wenjie.,...&Yan, Huaxiao.(2022).Evaluating the bioenergy potential of kitchen wastes fermentation residues through pyrolysis kinetics, thermodynamics and Py-GC/MS analysis technique.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,16.
MLA	Zhao, Hui,et al."Evaluating the bioenergy potential of kitchen wastes fermentation residues through pyrolysis kinetics, thermodynamics and Py-GC/MS analysis technique".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY (2022):16.