| Golden seaweed tides from beach inundations as a valuable sustainable fuel resource: Fast pyrolysis characteristics, product distribution and pathway study on Sargassum horneri based on model compounds | |
Li, Jie1,3,4 ; Zhu, Yanan1; Wang, Chengbiao1; Wei, Wei1; Liu, Zhengyi2; Tian, Yuanyu1,3,4; Zong, Peijie1; Qiao, Yingyun1,2,4; Qin, Song2
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| 发表期刊 | ALGAL RESEARCH-BIOMASS BIOFUELS AND BIOPRODUCTS
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| ISSN | 2211-9264 |
| 2020-06-01 | |
| 卷号 | 48页码:11 |
| 关键词 | Biomass Sargassum horneri Pyrolysis Mechanism Model compounds |
| DOI | 10.1016/j.algal.2020.101888 |
| 通讯作者 | Qiao, Yingyun(Qiao_yingyun@126.com) ; Qin, Song(sqin@yic.ac.cn) |
| 英文摘要 | This study investigates the pyrolysis characteristics and product distribution in the individual pyrolysis of Sargassum horneri (S. horneri) golden seaweed tide components (cellulose, protein and polysaccharide model compounds) and how the primary components lead to the observed product selectivity to explore their application as feedstocks for bio-oil production. The thermogravimetric analysis (DTG) curve of S. horneri was fitted by single pyrolysis curves of cellulose, protein and polysaccharide, which verified the feasibility of the selected model compounds. A higher heating rate significantly enhances the devolatilization performance of S. horneri and its main pseudocomponents. The fast pyrolysis of protein involves random cleavage of the main chain to form diketopiperazines (DKPs), and the side group will undergo cross-linking, cyclization, dehydroaromatization and other reactions to form amide/amines/nitriles, esters, hydrocarbons and N-heterocyclic compounds in particular. The fast pyrolysis of cellulose involves dehydration and 1,4-glycosidic bond-cleavage reactions as well as further rearrangement of intramolecular structures to form the intermediate product levoglucosan, secondary decomposition of levoglucosan to form aldehydes and ketones and rearrangement of intramolecular structures to form furan and its derivatives. The fast pyrolysis of polysaccharide involves depolymerization, dehydration, decarboxylation, decarbonylation and scission and condensation reactions to form lower molecular weight products, such as furfural, carbon dioxide, ketoesters and hydrocarbons. The results also indicate that the three main model compounds of S. horneri each exert a different influence on the product distribution under high-temperature pyrolysis. |
| 资助机构 | National Natural Science Foundation of China ; Taishan Scholar Foundation of Shandong Province ; Department of Science and Technology of Shandong Province ; Qingdao Municipal Science and Technology Bureau ; Fundamental Research Funds for the Central Universities ; Independent Innovation Research Project of China University of Petroleum (East China) ; Postgraduate Innovation Funding Project of China University of Petroleum (East China) |
| 收录类别 | SCI |
| 语种 | 英语 |
| 关键词[WOS] | HYDROGEN-RICH GAS ; BIO-OIL ; BIOMASS PYROLYSIS ; THERMAL-DEGRADATION ; CO-PYROLYSIS ; MICROWAVE PYROLYSIS ; CATALYTIC PYROLYSIS ; FLAME RETARDANCY ; BROWN SEAWEED ; TG-FTIR |
| 研究领域[WOS] | Biotechnology & Applied Microbiology |
| WOS记录号 | WOS:000539273100005 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.yic.ac.cn/handle/133337/28704 |
| 专题 | 海岸带生物学与生物资源利用重点实验室 海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室 |
| 通讯作者 | Qiao, Yingyun; Qin, Song |
| 作者单位 | 1.China Univ Petr East China, State Key Lab Heavy Oil Proc, Qingdao 266580, Shandong, Peoples R China 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264000, Shandong, Peoples R China 3.Shandong Univ Sci & Technol, Coll Chem & Environm Engn, Key Lab Low Carbon Energy & Chem Engn, Qingdao 266590, Shandong, Peoples R China 4.Shandong Engn & Technol Res Ctr High Carbon Energ, Qingdao 266590, Shandong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Jie,Zhu, Yanan,Wang, Chengbiao,et al. Golden seaweed tides from beach inundations as a valuable sustainable fuel resource: Fast pyrolysis characteristics, product distribution and pathway study on Sargassum horneri based on model compounds[J]. ALGAL RESEARCH-BIOMASS BIOFUELS AND BIOPRODUCTS,2020,48:11. |
| APA | Li, Jie.,Zhu, Yanan.,Wang, Chengbiao.,Wei, Wei.,Liu, Zhengyi.,...&Qin, Song.(2020).Golden seaweed tides from beach inundations as a valuable sustainable fuel resource: Fast pyrolysis characteristics, product distribution and pathway study on Sargassum horneri based on model compounds.ALGAL RESEARCH-BIOMASS BIOFUELS AND BIOPRODUCTS,48,11. |
| MLA | Li, Jie,et al."Golden seaweed tides from beach inundations as a valuable sustainable fuel resource: Fast pyrolysis characteristics, product distribution and pathway study on Sargassum horneri based on model compounds".ALGAL RESEARCH-BIOMASS BIOFUELS AND BIOPRODUCTS 48(2020):11. |
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