Cervidins A-D: Novel Glycine Conjugated Fatty Acids from the Tarsal Gland of Male Whitetail Deer, Odocoileus virginianus | |
Li, Ke1,2; Siefkes, Michael J.3; Li, Weiming1 | |
发表期刊 | JOURNAL OF CHEMICAL ECOLOGY |
ISSN | 0098-0331 |
2021-02-24 | |
页码 | 5 |
关键词 | Metabolites Deer Oxygenated fatty acids Glycine conjugates Integument |
DOI | 10.1007/s10886-021-01255-0 |
通讯作者 | Li, Weiming(liweim@msu.edu) |
英文摘要 | Sexually mature male deer are known to rub-urinate, a process where urine is deposited on the tarsal gland. The resulting mixture of compounds from urine and secretions from the tarsal gland are used to signal sex, age, maturation status, and other information at close distance. We examined the difference in metabolites of tarsal gland extracts from male and female whitetail deer, Odocoileus virginianus, harvested during the mating season. Using NMR spectroscopy and high-pressure liquid chromatography linked to high resolution mass spectrometry (HPLC/HR-MS) we identified a homologous series of four male-specific compounds. The compounds are novel glycine conjugates of 10-hydroxy-6,9-oxido fatty acids, which we term cervidins A-D. Cervidins were deemed to possess the absolute configuration 6S,9R,10R through comparison of their spectroscopic data with those of known compounds. In addition, cholesterol 3-sulfate and 3-(3-hydroxyphenyl)-propanoic acid were found to be present in the extracts. Our results clearly demonstrate the diversity of potential semiochemicals contained in the mammalian integument. |
收录类别 | SCI |
语种 | 英语 |
研究领域[WOS] | Biochemistry & Molecular Biology ; Environmental Sciences & Ecology |
WOS记录号 | WOS:000621260100001 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/27409 |
专题 | 海岸带生物学与生物资源利用重点实验室 海岸带生物学与生物资源利用重点实验室_海岸带生物资源高效利用研究与发展中心 |
通讯作者 | Li, Weiming |
作者单位 | 1.Michigan State Univ, Dept Fisheries & Wildlife, E Lansing, MI 48824 USA 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai, Peoples R China 3.Great Lakes Fishery Commiss, Ann Arbor, MI 48105 USA |
推荐引用方式 GB/T 7714 | Li, Ke,Siefkes, Michael J.,Li, Weiming. Cervidins A-D: Novel Glycine Conjugated Fatty Acids from the Tarsal Gland of Male Whitetail Deer, Odocoileus virginianus[J]. JOURNAL OF CHEMICAL ECOLOGY,2021:5. |
APA | Li, Ke,Siefkes, Michael J.,&Li, Weiming.(2021).Cervidins A-D: Novel Glycine Conjugated Fatty Acids from the Tarsal Gland of Male Whitetail Deer, Odocoileus virginianus.JOURNAL OF CHEMICAL ECOLOGY,5. |
MLA | Li, Ke,et al."Cervidins A-D: Novel Glycine Conjugated Fatty Acids from the Tarsal Gland of Male Whitetail Deer, Odocoileus virginianus".JOURNAL OF CHEMICAL ECOLOGY (2021):5. |
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