Thermogravimetric Analysis and Isoconversional Kinetic Study of Biomass Pyrolysis Derived from Land, Coastal Zone, and Marine | |
Li, J; Qiao, YY; Zong, PJ; Wang, CB; Tian, YY; Qin, S | |
发表期刊 | ENERGY & FUELS |
ISSN | 0887-0624 |
2019-04 | |
卷号 | 33期号:4页码:3299-3310 |
关键词 | CATALYTIC FAST PYROLYSIS LIGNOCELLULOSIC BIOMASS THERMAL-DEGRADATION ACTIVATION-ENERGY CO-PYROLYSIS MICROALGAE MODEL AROMATICS RESIDUES BIOFUELS |
研究领域 | Energy & Fuels ; Engineering, Chemical |
DOI | 10.1021/acs.energyfuels.9b00331 |
产权排序 | [Li, Jie; Qiao, Yingyun; Zong, Peijie; Wang, Chengbiao; Tian, Yuanyu] China Univ Petr East China, State Key Lab Heavy Oil Proc, Qingdao 266580, Shandong, Peoples R China; [Qin, Song] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264000, Peoples R China |
通讯作者 | Tian, Yuanyu(tianyy1008@126.com) ; Qin, Song(sqin@yic.ac.cn) |
作者部门 | 海岸带生物学与生物资源保护实验室 |
英文摘要 | Three types of biofuels derived from land, coastal zone, and marine were pyrolyzed in a thermogravimetric analyzer from room temperature to 1000 degrees C under different heating rates (50, 80, and 100 degrees C/min), and three isoconversional mathematical models were established to analyze the kinetic properties of biomass. The results show that the pyrolysis process of biomass derived from different distributions included three main stages: drying and preheating stage, volatile matter evaporation stage, and carbonization stage, whereas the pyrolysis behavior of the marine seawater Spirulina (Sp) biomass is somewhat different from that of land [corn stalks (Cs)] and coastal biomasses [reed (Re)], stemming from the inherent difference in their compositions. Cs and Re species have advantages over microalgae in terms of the difficulty of volatile matters releasing, whereas the pyrolysis process of Re and Sp is faster than Cs because of the catalysis of its high salt tolerance. The heating rate has a significant effect on the performance of devolatilization profiles and maximum weight loss rate, regardless of the biomass type from different regions. The dynamics analysis indicates that Sp species is preferable to Cs and Re in terms of thermochemical conversion because of the lower apparent activation energy for total conversion. From the verification test, we concluded that the simulations for Friedman models presented a good agreement with the experimental conversions calculated at three different heating rates for Cs, Re, and Sp pyrolysis, and that the kinetic simulation of the weight loss curve and kinetic parameters obtained by pyrolysis of three biomasses is reasonable and effective. |
文章类型 | Article |
资助机构 | National Natural Science Foundation of ChinaNational Natural Science Foundation of China [2157060571, 21576294, 21706287] ; Shandong Province Major Science and Technology Innovation Project [2018CXGC0301] ; Qingdao People's Livelihood Science and Technology Project [16-6-2-51-nsh, 18-6-1-101-nsh] ; Independent Innovation Research Project of China University of Petroleum (East China) [18CX05022A, YJ201601066] |
收录类别 | SCI |
语种 | 英语 |
关键词[WOS] | CATALYTIC FAST PYROLYSIS ; LIGNOCELLULOSIC BIOMASS ; THERMAL-DEGRADATION ; ACTIVATION-ENERGY ; CO-PYROLYSIS ; MICROALGAE ; MODEL ; AROMATICS ; RESIDUES ; BIOFUELS |
研究领域[WOS] | Energy & Fuels ; Engineering, Chemical |
WOS记录号 | WOS:000465486100061 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/24962 |
专题 | 海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室 |
作者单位 | 1.China Univ Petr East China, State Key Lab Heavy Oil Proc, Qingdao 266580, Shandong, Peoples R China; 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264000, Peoples R China |
推荐引用方式 GB/T 7714 | Li, J,Qiao, YY,Zong, PJ,et al. Thermogravimetric Analysis and Isoconversional Kinetic Study of Biomass Pyrolysis Derived from Land, Coastal Zone, and Marine[J]. ENERGY & FUELS,2019,33(4):3299-3310. |
APA | Li, J,Qiao, YY,Zong, PJ,Wang, CB,Tian, YY,&Qin, S.(2019).Thermogravimetric Analysis and Isoconversional Kinetic Study of Biomass Pyrolysis Derived from Land, Coastal Zone, and Marine.ENERGY & FUELS,33(4),3299-3310. |
MLA | Li, J,et al."Thermogravimetric Analysis and Isoconversional Kinetic Study of Biomass Pyrolysis Derived from Land, Coastal Zone, and Marine".ENERGY & FUELS 33.4(2019):3299-3310. |
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