Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
Solid-contact K+-selective electrode based on three-dimensional molybdenum sulfide nanoflowers as ion-to-electron transducer | |
Zeng, XZ; Yu, SY; Yuan, Q; Qin, W; Qin, W (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China. wqin@yic.ac.cn | |
发表期刊 | SENSORS AND ACTUATORS B-CHEMICAL |
ISSN | 0925-4005 |
2016-10-29 | |
卷号 | 234页码:80-83 |
关键词 | Mos2 Nanoflowers Solid Contact Ion-selective Electrodes Potentiometry Potassium |
DOI | 10.1016/j.snb.2016.04.153 |
产权排序 | [Zeng, Xianzhong; Yu, Shunyang; Qin, Wei] Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China; [Zeng, Xianzhong; Yu, Shunyang; Qin, Wei] YICCAS, Shandong Prov Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China; [Zeng, Xianzhong] Univ Chinese Acad Sci, Beijing 100039, Peoples R China; [Yuan, Qun] Yantai Univ, Coll Chem & Chem Engn, Yantai 264005, Peoples R China |
作者部门 | 中科院海岸带环境过程与生态修复重点实验室 |
英文摘要 | Three-dimensional (3D) molybdenum sulfide (MoS2) nanoflowers have been synthesized via a novel hydrothermal method and applied as ion-to-electron transducer for solid-contact ion-selective electrodes (SC-ISEs). The morphology and elemental composition of the prepared nanomaterials have been characterized. The performance of the developed K+-SC-ISE has been demonstrated by determining K+ in solution with a polymeric membrane containing valinomycin as the ionophore. A Nernstian slope of 55.8 mV/decade with a detection limit of 10(-5.5) M can be obtained. Using the 3D flowerlike MoS2 as solid contact, the fabricated K+-SC-ISE exhibits a smaller impedance and more stable potential response than the coated-wire electrode. In addition, the novel SC-ISE behaves well in the water layer test and shows good resistance to interferences from light, O-2 and CO2. It is believed that the 3D MoS2 nanoflowers can be a good alternative as solid contact in SC-ISEs. (C) 2016 Elsevier B.V. All rights reserved. |
文章类型 | Article |
资助机构 | Strategic Priority Research Program of the Chinese Academy of Sciences(XDA11020702) ; National Natural Science Foundation of China(21475148) ; Taishan Scholar Program of Shandong Province |
收录类别 | SCI |
语种 | 英语 |
关键词[WOS] | HYDROTHERMAL SYNTHESIS ; CARBON NANOTUBES ; MEMBRANE ; MOS2 ; LAYER ; NANOPARTICLES |
研究领域[WOS] | Chemistry ; Electrochemistry ; Instruments & Instrumentation |
WOS记录号 | WOS:000378538700011 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/17100 |
专题 | 中国科学院海岸带环境过程与生态修复重点实验室 |
通讯作者 | Qin, W (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China. wqin@yic.ac.cn |
作者单位 | 1.Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Environm Proc & Ecol Remediat 2.YICCAS, Shandong Prov Key Lab Coastal Environm Proc 3.Univ Chinese Acad Sci 4.Yantai Univ, Coll Chem & Chem Engn |
推荐引用方式 GB/T 7714 | Zeng, XZ,Yu, SY,Yuan, Q,et al. Solid-contact K+-selective electrode based on three-dimensional molybdenum sulfide nanoflowers as ion-to-electron transducer[J]. SENSORS AND ACTUATORS B-CHEMICAL,2016,234:80-83. |
APA | Zeng, XZ,Yu, SY,Yuan, Q,Qin, W,&Qin, W .(2016).Solid-contact K+-selective electrode based on three-dimensional molybdenum sulfide nanoflowers as ion-to-electron transducer.SENSORS AND ACTUATORS B-CHEMICAL,234,80-83. |
MLA | Zeng, XZ,et al."Solid-contact K+-selective electrode based on three-dimensional molybdenum sulfide nanoflowers as ion-to-electron transducer".SENSORS AND ACTUATORS B-CHEMICAL 234(2016):80-83. |
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