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Diterpenes from the brown alga Dictyota divaricata of the indian ocean
Ch.Bheemasankara Rao ; G. Trimurtulu ; D. Venkata Rao ; Steven C. Bobzina ; Diana M. Kushlana and D.John Faulkner
发表期刊Phytochemistry
1991
卷号30期号:6页码:1971-1976
关键词Dictyota Divaricata Dictyotaceae Dolabellanes Dolastanes Isodolastane
英文摘要The brown alga Dictyota divaricata from the coasts of the Andaman and Nicobar Islands in the Indian Ocean yielded one known and 11 new diterpenes of which four are dolabellanes, six are dolastanes, and one is a novel aromatic isodolastane. The structures of (1R*,3E,6S*,7E,11S*)-6- hydroxydolabella-3,7,12-triene, (1S*,3S*,4R*, 6S*,7E,11S*)-3,4-epoxy-6- hydroxydolabella-7,12-diene, (1R*,3Z,7E,11S*,12S*)-12-hydroxydolabella-3,7- dien-2-one, (1R*,3Z,7Z,11S*,12S*)-12-hydroxydolabella-3,8-dien-2-one, (1S*,11S*)-3,4;7,8-diepoxy-18-hydroxydolabella-12-ene, (5S*,8S*,9S*, 12R*,13R*,14R*)-9,13-dihydroxydolasta-1,3-diene, (5S*,8S*,9S*, 12R*,13R*,14R*)-13-acetoxy-9-hydroxydolasta-1,3-diene, (5R*,8S*,9 S*,12R*,14S*)-9-hydroxydolasta-1,3-dien-13-one, (5R*,8S*,9S*,12R*, 13S*,14S*)-9,13-dihydroxydolasta-1,3-diene, and (8S*,9S*,12R *)-9-hydroxyisodolasta-1,3,5(14)-trien-13-one were established by interpretation of spectral data and chemical interconversions. Two stereoisomers of (8S*,9S*,12S*)-9-hydroxydolasta-1,3-diene were isolated but their stereochemistries could not be completely elicidated.
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/4519
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Ch.Bheemasankara Rao,G. Trimurtulu,D. Venkata Rao,et al. Diterpenes from the brown alga Dictyota divaricata of the indian ocean[J]. Phytochemistry,1991,30(6):1971-1976.
APA Ch.Bheemasankara Rao,G. Trimurtulu,D. Venkata Rao,Steven C. Bobzina,&Diana M. Kushlana and D.John Faulkner.(1991).Diterpenes from the brown alga Dictyota divaricata of the indian ocean.Phytochemistry,30(6),1971-1976.
MLA Ch.Bheemasankara Rao,et al."Diterpenes from the brown alga Dictyota divaricata of the indian ocean".Phytochemistry 30.6(1991):1971-1976.
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