The invention belongs to the field of biotechnology, and specifically relates to a nanograde biocomposite and applications thereof. The nanograde biocomposite is prepared by mixing a nanograde oxidized grapheme-low molecular weight chitosan compound solution and a recombinant allophycocyanin solution with PBS solution, wherein the concentration of the nanograde oxidized grapheme-low molecular weight chitosan compound solution ranges from 0.02 to 10g/ml, and the concentration of the recombinant allophycocyanin solution ranges from 0.001 to 10mg/ml. The nanograde biocomposite can be uses as biosensors, is high in specificity and sensitivity, and is nanoscaled; and application range of the biocomposite is wide.
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