Synthesis and Metal-ion Binding Properties of New N2S4O2- and N2S5O2-Donor Macrocycles

YIC-IR > 科研共享资源

	Synthesis and Metal-ion Binding Properties of New N2S4O2- and N2S5O2-Donor Macrocycles
	Kantekin Halit ; Bakaray Asiye ; Ocak Miraç ; Alp Hakan ; Ocak Ümmühan
发表期刊	Separation Science and Technology
ISSN	0149-6395
	2007
卷号	42 期号:14 页码:3243-3257
关键词	Extraction Constant Solvent Extraction Mixed-donor Macrocycle Macrocyclic Complex TransitIon Metal Ion
英文摘要	Synthetic procedures for new mixed-donor macrocycle compounds were reported. The macrocyclic compounds were used in solvent extraction metal picrates such as Ag+, Hg2+, Cd2+, Zn2+, Cu2+, Ni2+, Mn2+, Pb2+, and Co2+. The metal picrate extractions were investigated at 25±0.1°C with the aid of UV-visible spectrometry. It was found that 6,7,9,10,12,13,23,24-octahydro-19H,26Hdibenzo[h,t](1,4,7,13,16,22,10,19) dioxatetrathiadiazasiclotetracosine-20,27(21H,28H)-dione showed selectivity towards Ag+, Hg2+, and Cd2+ among the other metals. The extraction constants (Log Kex) and complex compositions were determined for the Ag+ and Hg2+ complexes for this compound and 9,10,12,13,23,24,26,27,29,30-decahydro-5H,15H-dibenzo-[h,w][1,4,7,13,16,19,25-,10,22] dioxapentathiadiazacycloheptacosine-6,16(7H,17H)-dione.
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/3161
专题	科研共享资源
推荐引用方式 GB/T 7714	Kantekin Halit,Bakaray Asiye,Ocak Miraç,et al. Synthesis and Metal-ion Binding Properties of New N2S4O2- and N2S5O2-Donor Macrocycles[J]. Separation Science and Technology,2007,42(14):3243-3257.
APA	Kantekin Halit,Bakaray Asiye,Ocak Miraç,Alp Hakan,&Ocak Ümmühan.(2007).Synthesis and Metal-ion Binding Properties of New N2S4O2- and N2S5O2-Donor Macrocycles.Separation Science and Technology,42(14),3243-3257.
MLA	Kantekin Halit,et al."Synthesis and Metal-ion Binding Properties of New N2S4O2- and N2S5O2-Donor Macrocycles".Separation Science and Technology 42.14(2007):3243-3257.

条目包含的文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
Synthesis and Metal-（132KB）			限制开放	--	请求全文