Aniline chlorination by in situ formed Ag-Cl complexes under simulated solar light irradiation

	Aniline chlorination by in situ formed Ag-Cl complexes under simulated solar light irradiation
	Hu, XF; Wang, XW; Dong, LL; Chang, F; Luo, YM; Hu, XF (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China. xfhu@yic.ac.cn
发表期刊	WATER SCIENCE AND TECHNOLOGY
	2015
卷号	71 期号:11 页码:1679-1685
关键词	Aniline Ag-cl Complexes Cl/ag Ratio Photochlorination
产权排序	[Hu, Xuefeng; Wang, Xiaowen; Dong, Liuliu; Luo, Yongming] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China; [Hu, Xuefeng; Wang, Xiaowen; Luo, Yongming] Univ Chinese Acad Sci, Beijing 100049, Peoples R China; [Chang, Fei] Univ Shanghai Sci & Technol, Sch Environm & Architecture, Shanghai 200093, Peoples R China; [Dong, Liuliu] Yantai Univ, Environm & Mat Engn, Yantai 264005, Shandong, Peoples R China
作者部门	中科院海岸带环境过程与生态修复重点实验室
英文摘要	Ag speciation in a chloride medium was dependent upon the Cl/Ag ratio after releasing into surface water. In this study, the photoreaction of in situ formed Ag-Cl species and their effects on aniline photochlorination were systematically investigated. Our results suggested that formation of chloroaniline was strongly relevant to the Cl/Ag ratio and could be interpreted using the thermodynamically expected speciation of Ag in the presence of Cl-. AgCl was the main species responsible for the photochlorination of aniline. Both photoinduced hole and center dot OH drove the oxidation of Cl- to radical center dot Cl, which promoted the chlorination of aniline. Ag-0 formation was observed from the surface plasmon resonance absorption during AgCl photoreaction. This study revealed that Ag+ released into Cl--containing water may result in the formation of chlorinated intermediates of organic compounds under solar light irradiation.
文章类型	Article
收录类别	SCI
语种	英语
关键词[WOS]	AQUEOUS-SOLUTION ; RATE CONSTANTS ; SALINE WATER ; SILVER ; PHOTOCHLORINATION ; ACETONITRILE ; DEGRADATION ; MECHANISMS ; IONS
研究领域[WOS]	Engineering ; Environmental Sciences & Ecology ; Water Resources
WOS记录号	WOS:000355767100012
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/9255
专题	中国科学院海岸带环境过程与生态修复重点实验室
通讯作者	Hu, XF (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China. xfhu@yic.ac.cn
推荐引用方式 GB/T 7714	Hu, XF,Wang, XW,Dong, LL,et al. Aniline chlorination by in situ formed Ag-Cl complexes under simulated solar light irradiation[J]. WATER SCIENCE AND TECHNOLOGY,2015,71(11):1679-1685.
APA	Hu, XF,Wang, XW,Dong, LL,Chang, F,Luo, YM,&Hu, XF .(2015).Aniline chlorination by in situ formed Ag-Cl complexes under simulated solar light irradiation.WATER SCIENCE AND TECHNOLOGY,71(11),1679-1685.
MLA	Hu, XF,et al."Aniline chlorination by in situ formed Ag-Cl complexes under simulated solar light irradiation".WATER SCIENCE AND TECHNOLOGY 71.11(2015):1679-1685.

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