"One-drop-of-blood" electroanalysis of lead levels in blood using a foam-like mesoporous polymer of melamine-formaldehyde and disposable screen-printed electrodes
Zhao, Yanfang1,2; Xu, Lubin1,2; Li, Shuying1; Chen, Qi1; Yang, Daoshan1; Chen, Lingxin3; Wang, Hua1; Wang, H (reprint author) Qufu Normal Univ, Sch Chem & Chem Engn, Qufu City 273165, Peoples R China. huawangqfnu@126.com
发表期刊ANALYST
ISSN0003-2654
2015
卷号140期号:6页码:1832-1836
关键词Anodic-stripping Voltammetry Mercury-film Electrode Trace Heavy-metals Carbon Electrode Icp-ms Solid Sorbent Sensors Pb Cd Sensitivity
DOI10.1039 / c5an00039d
作者部门中科院海岸带环境过程与生态修复重点实验室
英文摘要A foam-like mesoporous polymer of melamine-formaldehyde (mPMF) was synthesized and further deposited on disposable screen-printed electrodes (SPEs) for the electroanalysis of Pb2+ ions in blood. Investigations indicate that the prepared mPMF is ultrastable in water, showing a mesoporous structure and an amine-rich composition, as characterized by electronic microscopy images and IR spectra. Importantly, it possesses a highly-selective chelating ability and a powerful absorbent capacity for Pb2+ ions. By way of solid-state PbCl2 voltammetry, the mPMF-modified sensor could allow for the detection of Pb2+ ions in one drop of blood with a high detection selectivity, sensitivity (down to about 0.10 mu g L-1 Pb2+ ions) and reproducibility. Such a simple "one-drop-of-blood" electroanalysis method equipped with disposable SPEs and a portable electrochemical transducer can be tailored for the field-deployable or on-site monitoring of blood Pb2+ levels in the clinical laboratory.
文章类型Article
资助机构National Natural Science Foundation of China (21375075 21302109 21302110) ; Taishan Scholar Foundation of Shandong Province, Domestic Visiting Scholar Foundation for Young Backbone Teachers of Department of Education, Shandong Province ; Qingdao Agricultural University High-Level Personnel Funds, Qingdao, P. R. China (630736)
收录类别SCI
语种英语
关键词[WOS]ANODIC-STRIPPING VOLTAMMETRY ; MERCURY-FILM ELECTRODE ; TRACE HEAVY-METALS ; CARBON ELECTRODE ; ICP-MS ; SOLID SORBENT ; SENSORS ; PB ; CD ; SENSITIVITY
研究领域[WOS]Chemistry
WOS记录号WOS:000350573400012
引用统计
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/9078
专题中国科学院海岸带环境过程与生态修复重点实验室
通讯作者Wang, H (reprint author) Qufu Normal Univ, Sch Chem & Chem Engn, Qufu City 273165, Peoples R China. huawangqfnu@126.com
作者单位1.Qufu Normal Univ, Sch Chem & Chem Engn, Qufu City 273165, Peoples R China
2.Qingdao Agr Univ, Coll Chem & Pharmaceut Sci, Qingdao 266109, Peoples R China
3.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remed, Yantai 264003, Peoples R China
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GB/T 7714
Zhao, Yanfang,Xu, Lubin,Li, Shuying,et al. "One-drop-of-blood" electroanalysis of lead levels in blood using a foam-like mesoporous polymer of melamine-formaldehyde and disposable screen-printed electrodes[J]. ANALYST,2015,140(6):1832-1836.
APA Zhao, Yanfang.,Xu, Lubin.,Li, Shuying.,Chen, Qi.,Yang, Daoshan.,...&Wang, H .(2015)."One-drop-of-blood" electroanalysis of lead levels in blood using a foam-like mesoporous polymer of melamine-formaldehyde and disposable screen-printed electrodes.ANALYST,140(6),1832-1836.
MLA Zhao, Yanfang,et al.""One-drop-of-blood" electroanalysis of lead levels in blood using a foam-like mesoporous polymer of melamine-formaldehyde and disposable screen-printed electrodes".ANALYST 140.6(2015):1832-1836.
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