Screening of Atmospheric Short- and Medium-Chain Chlorinated Paraffins in India and Pakistan using Polyurethane Foam Based Passive Air Sampler
Chaemfa, Chakra1; Xu, Yue1; Li, Jun1; Chakraborty, Paromita2; Syed, Jabir Hussain1; Malik, Riffat Naseem3; Wang, Yan1,4; Tian, Chongguo5,6; Zhang, Gan1; Jones, Kevin C.1,7; Chaemfa, C (reprint author), Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Organ Geochem, Guangzhou 510640, Guangdong, Peoples R China. chaemfa@gmail.com
发表期刊ENVIRONMENTAL SCIENCE & TECHNOLOGY
ISSN0013-936X
2014-05-06
卷号48期号:9页码:4799-4808
关键词Persistent Organic Pollutants Polybrominated Diphenyl Ethers Polychlorinated N-alkanes Pearl River Delta Organochlorine Pesticides Environmental Occurrence Mass-spectrometry Marine-sediments Indoor Air China
DOI10.1021/es405186m
产权排序[Chaemfa, Chakra; Xu, Yue; Li, Jun; Syed, Jabir Hussain; Wang, Yan; Zhang, Gan; Jones, Kevin C.] Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Organ Geochem, Guangzhou 510640, Guangdong, Peoples R China; [Chakraborty, Paromita] SRM Univ, SRN Res Inst, Kattankulathur, India; [Malik, Riffat Naseem] Quaid I Azam Univ, Dept Environm Sci, Environm Biol & Ecotoxicol Lab, Islamabad 45320, Pakistan; [Wang, Yan] Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn MOE, Dalian 116024, Peoples R China; [Tian, Chongguo] Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Yantai 264003, Shandong, Peoples R China; [Tian, Chongguo] YICCAS, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China; [Jones, Kevin C.] Univ Lancaster, Lancaster Environm Ctr, Lancaster LA1 4YQ, England
作者部门中科院海岸带环境过程与生态修复重点实验室
英文摘要Production and use of chlorinated paraffins (CPs) have been increasing in India. Distribution of CPs in the area and vicinity have become a great concern due to their persistency and toxicity. Polyurethane foam based passive air samplers (PUF-PAS) was deployed in order to screen the presence of short- and medium- chain chlorinated paraffins (SCCPs and MCCPs) in the outdoor atmosphere at many sites in India (in winter 2006) and Pakistan (in winter 2011). Concentrations of SCCPs and MCCPs ranged from not detected (ND) to 47.4 and 0 to 38.2 ng m(-3) with means of 8.11 and 4.83 ng m(-3), respectively. Indian concentrations showed higher average levels of both SCCPs and MCCPs India (10.2 ng m(-3) and 3.62 ng m(-3) than the samples from Pakistan (5.13 ng m(-3) and 4.21 ng m(-3)). Relative abundance patterns of carbon number are C10 > C11 > C12 similar to C13 for SCCPs and C14 > C15 > C16 C17 for MCCP with similarity to the profiles of samples from China, the biggest CPs producer in the world. Principal Component Analysis suggested that detected SCCPs and MCCPs in this study originated from the same emission source.; Production and use of chlorinated paraffins (CPs) have been increasing in India. Distribution of CPs in the area and vicinity have become a great concern due to their persistency and toxicity. Polyurethane foam based passive air samplers (PUF-PAS) was deployed in order to screen the presence of short- and medium- chain chlorinated paraffins (SCCPs and MCCPs) in the outdoor atmosphere at many sites in India (in winter 2006) and Pakistan (in winter 2011). Concentrations of SCCPs and MCCPs ranged from not detected (ND) to 47.4 and 0 to 38.2 ng m(-3) with means of 8.11 and 4.83 ng m(-3), respectively. Indian concentrations showed higher average levels of both SCCPs and MCCPs India (10.2 ng m(-3) and 3.62 ng m(-3) than the samples from Pakistan (5.13 ng m(-3) and 4.21 ng m(-3)). Relative abundance patterns of carbon number are C10 > C11 > C12 similar to C13 for SCCPs and C14 > C15 > C16 C17 for MCCP with similarity to the profiles of samples from China, the biggest CPs producer in the world. Principal Component Analysis suggested that detected SCCPs and MCCPs in this study originated from the same emission source.
文章类型Article
资助机构Engineering ; Environmental Sciences & Ecology
收录类别SCI
语种英语
关键词[WOS]PERSISTENT ORGANIC POLLUTANTS ; POLYBROMINATED DIPHENYL ETHERS ; POLYCHLORINATED N-ALKANES ; PEARL RIVER DELTA ; ORGANOCHLORINE PESTICIDES ; ENVIRONMENTAL OCCURRENCE ; MASS-SPECTROMETRY ; MARINE-SEDIMENTS ; INDOOR AIR ; CHINA
研究领域[WOS]Engineering ; Environmental Sciences & Ecology
WOS记录号WOS:000335720100021
引用统计
被引频次:61[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/8746
专题中国科学院海岸带环境过程与生态修复重点实验室
通讯作者Chaemfa, C (reprint author), Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Organ Geochem, Guangzhou 510640, Guangdong, Peoples R China. chaemfa@gmail.com
作者单位1.Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Organ Geochem, Guangzhou 510640, Guangdong, Peoples R China
2.SRM Univ, SRN Res Inst, Kattankulathur, India
3.Quaid I Azam Univ, Dept Environm Sci, Environm Biol & Ecotoxicol Lab, Islamabad 45320, Pakistan
4.Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn MOE, Dalian 116024, Peoples R China
5.Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Yantai 264003, Shandong, Peoples R China
6.YICCAS, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China
7.Univ Lancaster, Lancaster Environm Ctr, Lancaster LA1 4YQ, England
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Chaemfa, Chakra,Xu, Yue,Li, Jun,et al. Screening of Atmospheric Short- and Medium-Chain Chlorinated Paraffins in India and Pakistan using Polyurethane Foam Based Passive Air Sampler[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2014,48(9):4799-4808.
APA Chaemfa, Chakra.,Xu, Yue.,Li, Jun.,Chakraborty, Paromita.,Syed, Jabir Hussain.,...&Chaemfa, C .(2014).Screening of Atmospheric Short- and Medium-Chain Chlorinated Paraffins in India and Pakistan using Polyurethane Foam Based Passive Air Sampler.ENVIRONMENTAL SCIENCE & TECHNOLOGY,48(9),4799-4808.
MLA Chaemfa, Chakra,et al."Screening of Atmospheric Short- and Medium-Chain Chlorinated Paraffins in India and Pakistan using Polyurethane Foam Based Passive Air Sampler".ENVIRONMENTAL SCIENCE & TECHNOLOGY 48.9(2014):4799-4808.
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