Characteristics and Potential Health Hazards of Organochlorine Pesticides in Shallow Groundwater of Two Cities in the Yangtze River Delta
Wu, Chunfa1; Luo, Yongming2; Gui, Tong3; Yan, Shihong4; Wu, CF (reprint author), Nanjing Univ Informat Sci & Technol, 219 Ningliu Rd, Nanjing 210044, Jiangsu, Peoples R China. wchf1680@sina.com
发表期刊CLEAN-SOIL AIR WATER
ISSN1863-0650
2014-07-01
卷号42期号:7页码:923-931
关键词Ddt Health Risk Assessment Hexachlorohexane Isomers Metabolites
DOI10.1002/clen.201200602
产权排序[Wu, Chunfa] Nanjing Univ Informat Sci & Technol, Nanjing 210044, Jiangsu, Peoples R China; [Luo, Yongming] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai, Peoples R China; [Gui, Tong] Jiangsu Univ Sci & Technol, Coll Biol & Environm Engn, Zhenjiang, Jiangsu, Peoples R China; [Yan, Shihong] Anhui Univ Sci & Technol, Sch Earth & Environm, Huainan, Peoples R China
作者部门中科院海岸带环境过程与生态修复重点实验室
英文摘要A total of 52 shallow groundwater samples were collected from two cities, Shengzhou and Shangyu, in the Yangtze River Delta, to characterize the residues of hexachlorocyclohexane (HCH) isomers and dichlorodiphenyltrichloroethane (DDT) isomers/metabolites present and estimate health risk of drinking groundwater. HCH and DDT residues occurred in the shallow groundwater of most of Shengzhou and partial area of Shangyu. Concentrations of total HCH (Sigma HCHs) and total DDT (Sigma DDTs) in the shallow groundwater ranged from below the detection limit (BDL) to 123.2 ng L-1 and BDL to 321.4 ng L-1 for Shengzhou and BDL to 46.40 ng L(-1)and BDL to 77.92 ng L-1 for Shangyu. The predominant HCH and DDT species in the shallow groundwater of Shengzhou were delta-HCH and o, p'-DDT, and the equivalent species in Shangyu were d-HCH and p, p'-DDT. The low alpha-HCH/gamma-HCH ratio, low (dichlorodiphenylethylene (DDE) + dichlorodiphenyldichloroethane)/Sigma DDTs ratio and o, p'-DDE being the dominant DDT metabolite for the majority of samples collected from Shengzhou suggest that there are fresh inputs of lindane and dicofol mixtures in majority area of Shengzhou. The high ratios of p, p'-DDT/SDDTs in half of the groundwater samples collected from Shangyu suggest that there are fresh inputs of DDT in partial area of Shangyu. alpha-HCH, beta-HCH, and gamma-HCH in the shallow groundwater in majority area of Shengzhou are posing serious cancer risks to children (> 10(-6)), and the three HCH isomers in the shallow groundwater of Shengzhou should be controlled urgently and effectively.; A total of 52 shallow groundwater samples were collected from two cities, Shengzhou and Shangyu, in the Yangtze River Delta, to characterize the residues of hexachlorocyclohexane (HCH) isomers and dichlorodiphenyltrichloroethane (DDT) isomers/metabolites present and estimate health risk of drinking groundwater. HCH and DDT residues occurred in the shallow groundwater of most of Shengzhou and partial area of Shangyu. Concentrations of total HCH (Sigma HCHs) and total DDT (Sigma DDTs) in the shallow groundwater ranged from below the detection limit (BDL) to 123.2 ng L-1 and BDL to 321.4 ng L-1 for Shengzhou and BDL to 46.40 ng L(-1)and BDL to 77.92 ng L-1 for Shangyu. The predominant HCH and DDT species in the shallow groundwater of Shengzhou were delta-HCH and o, p'-DDT, and the equivalent species in Shangyu were d-HCH and p, p'-DDT. The low alpha-HCH/gamma-HCH ratio, low (dichlorodiphenylethylene (DDE) + dichlorodiphenyldichloroethane)/Sigma DDTs ratio and o, p'-DDE being the dominant DDT metabolite for the majority of samples collected from Shengzhou suggest that there are fresh inputs of lindane and dicofol mixtures in majority area of Shengzhou. The high ratios of p, p'-DDT/SDDTs in half of the groundwater samples collected from Shangyu suggest that there are fresh inputs of DDT in partial area of Shangyu. alpha-HCH, beta-HCH, and gamma-HCH in the shallow groundwater in majority area of Shengzhou are posing serious cancer risks to children (> 10(-6)), and the three HCH isomers in the shallow groundwater of Shengzhou should be controlled urgently and effectively.
文章类型Article
资助机构Environmental Sciences & Ecology ; Marine & Freshwater Biology ; Water Resources
收录类别SCI
语种英语
关键词[WOS]HEXACHLOROCYCLOHEXANE ISOMERS ; CHLORINATED HYDROCARBONS ; ATMOSPHERIC TRANSPORT ; RISK-ASSESSMENT ; QIANTANG RIVER ; SURFACE-WATER ; HONG-KONG ; CHINA ; RESIDUES ; SEDIMENTS
研究领域[WOS]Environmental Sciences & Ecology ; Marine & Freshwater Biology ; Water Resources
WOS记录号WOS:000339476200008
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/8729
专题中国科学院海岸带环境过程与生态修复重点实验室
通讯作者Wu, CF (reprint author), Nanjing Univ Informat Sci & Technol, 219 Ningliu Rd, Nanjing 210044, Jiangsu, Peoples R China. wchf1680@sina.com
作者单位1.Nanjing Univ Informat Sci & Technol, Nanjing 210044, Jiangsu, Peoples R China
2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai, Peoples R China
3.Jiangsu Univ Sci & Technol, Coll Biol & Environm Engn, Zhenjiang, Jiangsu, Peoples R China
4.Anhui Univ Sci & Technol, Sch Earth & Environm, Huainan, Peoples R China
推荐引用方式
GB/T 7714
Wu, Chunfa,Luo, Yongming,Gui, Tong,et al. Characteristics and Potential Health Hazards of Organochlorine Pesticides in Shallow Groundwater of Two Cities in the Yangtze River Delta[J]. CLEAN-SOIL AIR WATER,2014,42(7):923-931.
APA Wu, Chunfa,Luo, Yongming,Gui, Tong,Yan, Shihong,&Wu, CF .(2014).Characteristics and Potential Health Hazards of Organochlorine Pesticides in Shallow Groundwater of Two Cities in the Yangtze River Delta.CLEAN-SOIL AIR WATER,42(7),923-931.
MLA Wu, Chunfa,et al."Characteristics and Potential Health Hazards of Organochlorine Pesticides in Shallow Groundwater of Two Cities in the Yangtze River Delta".CLEAN-SOIL AIR WATER 42.7(2014):923-931.
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