Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
| Graphene oxide-based microspheres for the dispersive solid-phase extraction of non-steroidal estrogens from water samples | |
Wen, Yingying1,2; Niu, Zongliang1; Ma, Yanling2; Ma, Jiping3; Chen, Lingxin2 ; Chen, LX (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remedia, Yantai 264003, Peoples R China. lxchen@yic.ac.cn
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| 发表期刊 | JOURNAL OF CHROMATOGRAPHY A
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| ISSN | 0021-9673 |
| 2014-11-14 | |
| 卷号 | 1368页码:18-25 |
| 关键词 | Non-steroidal Estrogens Graphene Oxide Dispersive Solid-phase Extraction High Performance Liquid Chromatography |
| DOI | 10.1016/j.chroma.2014.09.049 |
| 产权排序 | [Wen, Yingying; Niu, Zongliang] Hainan Med Univ, Sch Trop & Lab Med, Environm Monitoring Lab, Haikou 571199, Peoples R China; [Wen, Yingying; Ma, Yanling; Chen, Lingxin] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remedia, Yantai 264003, Peoples R China; [Ma, Jiping] Qingdao Technol Univ, Sch Environm & Municipal Engn, Key Lab Environm Engn Shandong Prov, Qingdao 266033, Peoples R China |
| 作者部门 | 中科院海岸带环境过程与生态修复重点实验室 |
| 英文摘要 | A modified Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) method based on the dispersive solid-phase extraction (dSPE) combined with high performance liquid chromatography (HPLC) was developed for the determination of non-steroidal estrogens in water samples. In this study, graphene oxide-based silica microspheres (SiO2@GO) were used as dSPE material for the preconcentration of analytes. HPLC was used for the separation and detection. This was the first time that the synthesized SiO2@GO microspheres were used as stationary phases for the off-line preconcentration of the non-steroidal estrogens in dSPE. dSPE parameters, such as sample pH, volume and type of eluent were optimized. Application of the developed method to analyze spiked lake, reservoir and tap water samples resulted in good recoveries values ranging from 70 to 106% with relative standard deviation values lower than 7.0% in all cases. Limits of detection were in the range of 0.2-6.1 mu g/L. The combined data obtained in this study recommended that the proposed method is very fast, simple, repeatable and accurate for the detection of non-steroidal estrogens. Furthermore, the SiO2@GO microspheres application could potentially be expanded to extract and pre-concentrate other compounds in various matrices. (C) 2014 Elsevier B.V. All rights reserved.; A modified Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) method based on the dispersive solid-phase extraction (dSPE) combined with high performance liquid chromatography (HPLC) was developed for the determination of non-steroidal estrogens in water samples. In this study, graphene oxide-based silica microspheres (SiO2@GO) were used as dSPE material for the preconcentration of analytes. HPLC was used for the separation and detection. This was the first time that the synthesized SiO2@GO microspheres were used as stationary phases for the off-line preconcentration of the non-steroidal estrogens in dSPE. dSPE parameters, such as sample pH, volume and type of eluent were optimized. Application of the developed method to analyze spiked lake, reservoir and tap water samples resulted in good recoveries values ranging from 70 to 106% with relative standard deviation values lower than 7.0% in all cases. Limits of detection were in the range of 0.2-6.1 mu g/L. The combined data obtained in this study recommended that the proposed method is very fast, simple, repeatable and accurate for the detection of non-steroidal estrogens. Furthermore, the SiO2@GO microspheres application could potentially be expanded to extract and pre-concentrate other compounds in various matrices. (C) 2014 Elsevier B.V. All rights reserved. |
| 文章类型 | Article |
| 资助机构 | Biochemistry & Molecular Biology ; Chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| 关键词[WOS] | PERFORMANCE LIQUID-CHROMATOGRAPHY ; TANDEM MASS-SPECTROMETRY ; WALLED CARBON NANOTUBES ; CLOUD-POINT EXTRACTION ; GAS-CHROMATOGRAPHY ; CAPILLARY-ELECTROPHORESIS ; ENVIRONMENTAL ESTROGENS ; PESTICIDE-RESIDUES ; SEWAGE-SLUDGE ; MICROEXTRACTION |
| 研究领域[WOS] | Biochemistry & Molecular Biology ; Chemistry |
| WOS记录号 | WOS:000344437500002 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.yic.ac.cn/handle/133337/8694 |
| 专题 | 中国科学院海岸带环境过程与生态修复重点实验室 |
| 通讯作者 | Chen, LX (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remedia, Yantai 264003, Peoples R China. lxchen@yic.ac.cn |
| 作者单位 | 1.Hainan Med Univ, Sch Trop & Lab Med, Environm Monitoring Lab, Haikou 571199, Peoples R China 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remedia, Yantai 264003, Peoples R China 3.Qingdao Technol Univ, Sch Environm & Municipal Engn, Key Lab Environm Engn Shandong Prov, Qingdao 266033, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wen, Yingying,Niu, Zongliang,Ma, Yanling,et al. Graphene oxide-based microspheres for the dispersive solid-phase extraction of non-steroidal estrogens from water samples[J]. JOURNAL OF CHROMATOGRAPHY A,2014,1368:18-25. |
| APA | Wen, Yingying,Niu, Zongliang,Ma, Yanling,Ma, Jiping,Chen, Lingxin,&Chen, LX .(2014).Graphene oxide-based microspheres for the dispersive solid-phase extraction of non-steroidal estrogens from water samples.JOURNAL OF CHROMATOGRAPHY A,1368,18-25. |
| MLA | Wen, Yingying,et al."Graphene oxide-based microspheres for the dispersive solid-phase extraction of non-steroidal estrogens from water samples".JOURNAL OF CHROMATOGRAPHY A 1368(2014):18-25. |
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