Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
Single-Piece Solid-Contact Polymeric Membrane Ion-Selective Electrodes for Silver Ion | |
Yin, Tanji1,2,3; Liu, Yuanyuan1,4; Qin, Wei1; Yin, TJ (reprint author), Chinese Acad Sci, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Shandong, Peoples R China. tjyin@yic.ac.cn | |
发表期刊 | JOURNAL OF THE ELECTROCHEMICAL SOCIETY |
ISSN | 0013-4651 |
2013 | |
卷号 | 160期号:8页码:B91-B94 |
关键词 | State Chloride Sensors Potentiometric Sensors Nanoparticles Polyaniline Composites Transducer |
产权排序 | [Yin, Tanji; Liu, Yuanyuan; Qin, Wei] Chinese Acad Sci, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Shandong, Peoples R China; [Yin, Tanji] Chinese Acad Sci, South China Sea Inst Oceanol, Guangzhou 510301, Guangdong, Peoples R China; [Yin, Tanji] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China; [Liu, Yuanyuan] Yantai Univ, Coll Chem & Biol, Yantai 264005, Peoples R China |
英文摘要 | Single-piece solid-contact polymeric membrane Ag+ ion-selective electrodes (ISEs) have been fabricated based on conducting polymer poly(3-octylthiophene) (POT) dissolved into the Ag+ ion-selective membrane. The effects of the amounts of POT on the potential responses of the single-piece solid-contact Ag+-ISEs were investigated in detail. Results indicate that the single-piece solid-contact Ag+-ISE with 10 wt% POT displays excellent reproducibility and stability of the potential response. The linear range of 3.0 x 10(-8)-3.0 x 10(-5) M can be obtained in AgNO3 solution with the slope 56.84 +/- 0.92 mV/dec (n = 3, R = 0.9984) and the detection limit is 1.90 x 10(-8) M. In addition, the single-piece solid-contact Ag+-ISE with 10 wt% POT shows excellent selectivity, stable potential response over a pH range of 3.5 to 6.0 and no significant redox sensitivity. The proposed electrode with 10 wt% POT has been successfully applied to potentiometric titration of chloride ion and determination of Ag+ ion concentrations in spiked waters with high accuracy and good reliability. (C) 2013 The Electrochemical Society. |
文章类型 | Article |
资助机构 | Outstanding Youth National Science Foundation of Shandong Province [JQ200814]; National Natural Science Foundation of China [20977073]; Taishan Scholar Program of Shandong Province [TS20081159] |
收录类别 | SCI |
语种 | 英语 |
关键词[WOS] | STATE CHLORIDE SENSORS ; POTENTIOMETRIC SENSORS ; NANOPARTICLES ; POLYANILINE ; COMPOSITES ; TRANSDUCER |
研究领域[WOS] | Electrochemistry ; Materials Science |
WOS记录号 | WOS:000324810000047 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/6991 |
专题 | 中国科学院海岸带环境过程与生态修复重点实验室 |
通讯作者 | Yin, TJ (reprint author), Chinese Acad Sci, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Shandong, Peoples R China. tjyin@yic.ac.cn |
作者单位 | 1.Chinese Acad Sci, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Shandong, Peoples R China 2.Chinese Acad Sci, South China Sea Inst Oceanol, Guangzhou 510301, Guangdong, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 4.Yantai Univ, Coll Chem & Biol, Yantai 264005, Peoples R China |
推荐引用方式 GB/T 7714 | Yin, Tanji,Liu, Yuanyuan,Qin, Wei,et al. Single-Piece Solid-Contact Polymeric Membrane Ion-Selective Electrodes for Silver Ion[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2013,160(8):B91-B94. |
APA | Yin, Tanji,Liu, Yuanyuan,Qin, Wei,&Yin, TJ .(2013).Single-Piece Solid-Contact Polymeric Membrane Ion-Selective Electrodes for Silver Ion.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,160(8),B91-B94. |
MLA | Yin, Tanji,et al."Single-Piece Solid-Contact Polymeric Membrane Ion-Selective Electrodes for Silver Ion".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 160.8(2013):B91-B94. |
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