Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
Simultaneous removal of arsenate and arsenite by a nanostructured zirconium-manganese binary hydrous oxide: Behavior and mechanism | |
Zhang, Gaosheng1,2,3; Khorshed, Alam1; Chen, J. Paul1 | |
发表期刊 | JOURNAL OF COLLOID AND INTERFACE SCIENCE |
ISSN | 0021-9797 |
2013-05-01 | |
卷号 | 397页码:137-143 |
关键词 | Zr-mn Binary Hydrous Oxide Arsenate Arsenite Adsorption Oxidation |
产权排序 | [Zhang, Gaosheng; Khorshed, Alam; Chen, J. Paul] Natl Univ Singapore, Dept Civil & Environm Engn, Singapore 117576, Singapore; [Zhang, Gaosheng] Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China; [Zhang, Gaosheng] Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China |
通讯作者 | Zhang, GS (reprint author), Natl Univ Singapore, Dept Civil & Environm Engn, 1 Engn Dr 2, Singapore 117576, Singapore. gszhang@yic.ac.cn ; paulchen@nus.edu.sg |
作者部门 | 中科院海岸带环境过程与生态修复重点实验室 |
英文摘要 | Arsenate and arsenite typically co-exist in groundwater. Arsenite is more toxic than arsenate, while it is more difficult to be removed than arsenate. In order to effectively remove arsenate and arsenite simultaneously from water solution, a nanostructured zirconium-manganese binary hydrous oxide was successfully developed in this study. The amorphous sorbent was aggregate of nanoparticles with a high surface area of 213 m(2) g(-1). Our sorption experiments showed that the nano-scale particles could effectively oxidize As(III) to As(V) and greatly remove both As(V) and As(III). The maximal adsorption capacities of As(V) and As(III) were 80 and 104 mg g(-1) at pH 5.0, respectively. As(V) uptake may be mainly achieved through replacement of hydroxyl groups and sulfate anions on the surface of the oxide and formation of inner complexes. The As(III) removal was essentially due to a sorption coupled with oxidation process; the MnO2 was mainly responsible for oxidization of As(III) to As(V) that was subsequently adsorbed onto ZrO2. (C) 2012 Elsevier Inc. All rights reserved.; Arsenate and arsenite typically co-exist in groundwater. Arsenite is more toxic than arsenate, while it is more difficult to be removed than arsenate. In order to effectively remove arsenate and arsenite simultaneously from water solution, a nanostructured zirconium-manganese binary hydrous oxide was successfully developed in this study. The amorphous sorbent was aggregate of nanoparticles with a high surface area of 213 m(2) g(-1). Our sorption experiments showed that the nano-scale particles could effectively oxidize As(III) to As(V) and greatly remove both As(V) and As(III). The maximal adsorption capacities of As(V) and As(III) were 80 and 104 mg g(-1) at pH 5.0, respectively. As(V) uptake may be mainly achieved through replacement of hydroxyl groups and sulfate anions on the surface of the oxide and formation of inner complexes. The As(III) removal was essentially due to a sorption coupled with oxidation process; the MnO2 was mainly responsible for oxidization of As(III) to As(V) that was subsequently adsorbed onto ZrO2. (C) 2012 Elsevier Inc. All rights reserved. |
文章类型 | Article |
资助机构 | National Research Foundation of Singapore [R-302-000-026-281]; National Natural Science Foundation of China [51178453] |
收录类别 | SCI |
语种 | 英语 |
关键词[WOS] | TITANIUM-DIOXIDE ; IRON-OXIDE ; ADSORPTION ; AS(III) ; ADSORBENT ; AS(V) ; SORPTION ; SURFACE ; XPS ; SPECTROSCOPY |
研究领域[WOS] | Chemistry |
WOS记录号 | WOS:000316776600018 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/6670 |
专题 | 中国科学院海岸带环境过程与生态修复重点实验室 中国科学院海岸带环境过程与生态修复重点实验室_污染过程与控制实验室 |
作者单位 | 1.Natl Univ Singapore, Dept Civil & Environm Engn, Singapore 117576, Singapore 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China 3.Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Gaosheng,Khorshed, Alam,Chen, J. Paul. Simultaneous removal of arsenate and arsenite by a nanostructured zirconium-manganese binary hydrous oxide: Behavior and mechanism[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2013,397:137-143. |
APA | Zhang, Gaosheng,Khorshed, Alam,&Chen, J. Paul.(2013).Simultaneous removal of arsenate and arsenite by a nanostructured zirconium-manganese binary hydrous oxide: Behavior and mechanism.JOURNAL OF COLLOID AND INTERFACE SCIENCE,397,137-143. |
MLA | Zhang, Gaosheng,et al."Simultaneous removal of arsenate and arsenite by a nanostructured zirconium-manganese binary hydrous oxide: Behavior and mechanism".JOURNAL OF COLLOID AND INTERFACE SCIENCE 397(2013):137-143. |
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