Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
Potentiometric sensor for determination of neutral bisphenol A using a molecularly imprinted polymer as a receptor | |
Kou, Li-Juan1,2,3; Liang, Rong-Ning1,3; Wang, Xue-Wei1,2,3; Chen, Yan1,3; Qin, Wei1,3 | |
发表期刊 | ANALYTICAL AND BIOANALYTICAL CHEMISTRY |
ISSN | 1618-2642 |
2013-05-01 | |
卷号 | 405期号:14页码:4931-4936 |
关键词 | Molecularly Imprinted Polymers Ion-selective Electrodes Bisphenol a Phenols |
产权排序 | [Kou, Li-Juan; Liang, Rong-Ning; Wang, Xue-Wei; Chen, Yan; Qin, Wei] Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Yantai 264003, Shandong, Peoples R China; [Kou, Li-Juan; Wang, Xue-Wei] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China; [Kou, Li-Juan; Liang, Rong-Ning; Wang, Xue-Wei; Chen, Yan; Qin, Wei] YICCAS, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China |
通讯作者 | Qin, W (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Yantai 264003, Shandong, Peoples R China. wqin@yic.ac.cn |
作者部门 | 中科院海岸带环境过程与生态修复重点实验室 |
英文摘要 | The aim of this paper is to develop a potentiometric sensing methodology for sensitive and selective determination of neutral phenols by using a molecularly imprinted polymer as a receptor. Bisphenol A (BPA), a significant environmental contaminant, is employed as the model target. The BPA-imprinted polymer is synthesized by the semi-covalent technique and incorporated into a plasticized poly(vinyl chloride) membrane doped with the tridodecylmethylammonium salt. The present electrode shows a linear anionic potential response over the concentration range from 0.1 to 1 mu M with a detection limit of 0.02 mu M, and exhibits an excellent selectivity over other phenols. The proposed approach has been successfully applied to the determination of BPA released from real plastic samples. It offers promising potential in development of potentiometric sensors for measuring neutral phenols at trace levels.; The aim of this paper is to develop a potentiometric sensing methodology for sensitive and selective determination of neutral phenols by using a molecularly imprinted polymer as a receptor. Bisphenol A (BPA), a significant environmental contaminant, is employed as the model target. The BPA-imprinted polymer is synthesized by the semi-covalent technique and incorporated into a plasticized poly(vinyl chloride) membrane doped with the tridodecylmethylammonium salt. The present electrode shows a linear anionic potential response over the concentration range from 0.1 to 1 mu M with a detection limit of 0.02 mu M, and exhibits an excellent selectivity over other phenols. The proposed approach has been successfully applied to the determination of BPA released from real plastic samples. It offers promising potential in development of potentiometric sensors for measuring neutral phenols at trace levels. |
文章类型 | Article |
资助机构 | Instrument Developing Project of the Chinese Academy of Sciences [YZ201161]; National Natural Science Foundation of China [20977073, 41206087]; Taishan Scholar Program of Shandong Province [TS20081159] |
收录类别 | SCI |
语种 | 英语 |
关键词[WOS] | SOLID-PHASE EXTRACTION ; MEMBRANE ; ELECTRODES ; MECHANISM ; SAMPLES ; WATER ; MILK |
研究领域[WOS] | Biochemistry & Molecular Biology ; Chemistry |
WOS记录号 | WOS:000318312400026 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/6654 |
专题 | 中国科学院海岸带环境过程与生态修复重点实验室 |
作者单位 | 1.Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Yantai 264003, Shandong, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.YICCAS, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China |
推荐引用方式 GB/T 7714 | Kou, Li-Juan,Liang, Rong-Ning,Wang, Xue-Wei,et al. Potentiometric sensor for determination of neutral bisphenol A using a molecularly imprinted polymer as a receptor[J]. ANALYTICAL AND BIOANALYTICAL CHEMISTRY,2013,405(14):4931-4936. |
APA | Kou, Li-Juan,Liang, Rong-Ning,Wang, Xue-Wei,Chen, Yan,&Qin, Wei.(2013).Potentiometric sensor for determination of neutral bisphenol A using a molecularly imprinted polymer as a receptor.ANALYTICAL AND BIOANALYTICAL CHEMISTRY,405(14),4931-4936. |
MLA | Kou, Li-Juan,et al."Potentiometric sensor for determination of neutral bisphenol A using a molecularly imprinted polymer as a receptor".ANALYTICAL AND BIOANALYTICAL CHEMISTRY 405.14(2013):4931-4936. |
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