Potentiometric sensor for determination of neutral bisphenol A using a molecularly imprinted polymer as a receptor
Kou, Li-Juan1,2,3; Liang, Rong-Ning1,3; Wang, Xue-Wei1,2,3; Chen, Yan1,3; Qin, Wei1,3
发表期刊ANALYTICAL AND BIOANALYTICAL CHEMISTRY
ISSN1618-2642
2013-05-01
卷号405期号:14页码:4931-4936
关键词Molecularly Imprinted Polymers Ion-selective Electrodes Bisphenol a Phenols
产权排序[Kou, Li-Juan; Liang, Rong-Ning; Wang, Xue-Wei; Chen, Yan; Qin, Wei] Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Yantai 264003, Shandong, Peoples R China; [Kou, Li-Juan; Wang, Xue-Wei] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China; [Kou, Li-Juan; Liang, Rong-Ning; Wang, Xue-Wei; Chen, Yan; Qin, Wei] YICCAS, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China
通讯作者Qin, W (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Yantai 264003, Shandong, Peoples R China. wqin@yic.ac.cn
作者部门中科院海岸带环境过程与生态修复重点实验室
英文摘要The aim of this paper is to develop a potentiometric sensing methodology for sensitive and selective determination of neutral phenols by using a molecularly imprinted polymer as a receptor. Bisphenol A (BPA), a significant environmental contaminant, is employed as the model target. The BPA-imprinted polymer is synthesized by the semi-covalent technique and incorporated into a plasticized poly(vinyl chloride) membrane doped with the tridodecylmethylammonium salt. The present electrode shows a linear anionic potential response over the concentration range from 0.1 to 1 mu M with a detection limit of 0.02 mu M, and exhibits an excellent selectivity over other phenols. The proposed approach has been successfully applied to the determination of BPA released from real plastic samples. It offers promising potential in development of potentiometric sensors for measuring neutral phenols at trace levels.; The aim of this paper is to develop a potentiometric sensing methodology for sensitive and selective determination of neutral phenols by using a molecularly imprinted polymer as a receptor. Bisphenol A (BPA), a significant environmental contaminant, is employed as the model target. The BPA-imprinted polymer is synthesized by the semi-covalent technique and incorporated into a plasticized poly(vinyl chloride) membrane doped with the tridodecylmethylammonium salt. The present electrode shows a linear anionic potential response over the concentration range from 0.1 to 1 mu M with a detection limit of 0.02 mu M, and exhibits an excellent selectivity over other phenols. The proposed approach has been successfully applied to the determination of BPA released from real plastic samples. It offers promising potential in development of potentiometric sensors for measuring neutral phenols at trace levels.
文章类型Article
资助机构Instrument Developing Project of the Chinese Academy of Sciences [YZ201161]; National Natural Science Foundation of China [20977073, 41206087]; Taishan Scholar Program of Shandong Province [TS20081159]
收录类别SCI
语种英语
关键词[WOS]SOLID-PHASE EXTRACTION ; MEMBRANE ; ELECTRODES ; MECHANISM ; SAMPLES ; WATER ; MILK
研究领域[WOS]Biochemistry & Molecular Biology ; Chemistry
WOS记录号WOS:000318312400026
引用统计
被引频次:41[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/6654
专题中国科学院海岸带环境过程与生态修复重点实验室
作者单位1.Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Yantai 264003, Shandong, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.YICCAS, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China
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GB/T 7714
Kou, Li-Juan,Liang, Rong-Ning,Wang, Xue-Wei,et al. Potentiometric sensor for determination of neutral bisphenol A using a molecularly imprinted polymer as a receptor[J]. ANALYTICAL AND BIOANALYTICAL CHEMISTRY,2013,405(14):4931-4936.
APA Kou, Li-Juan,Liang, Rong-Ning,Wang, Xue-Wei,Chen, Yan,&Qin, Wei.(2013).Potentiometric sensor for determination of neutral bisphenol A using a molecularly imprinted polymer as a receptor.ANALYTICAL AND BIOANALYTICAL CHEMISTRY,405(14),4931-4936.
MLA Kou, Li-Juan,et al."Potentiometric sensor for determination of neutral bisphenol A using a molecularly imprinted polymer as a receptor".ANALYTICAL AND BIOANALYTICAL CHEMISTRY 405.14(2013):4931-4936.
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