Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
| Water-Miscible Room-Temperature Ionic Liquid-Cobalt Hexacyanoferrate Gel Modified Electrode for Electrocatalytic Oxidation of NADH | |
Zhang, Qing1; Zhu, Rilong2; Kang, Qi1; Lu, Wenjing3,4; Zhang, Haiyun3,4; Pan, Dawei3,4
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| 发表期刊 | INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
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| ISSN | 1452-3981 |
| 2012-09-01 | |
| 卷号 | 7期号:9页码:8185-8193 |
| 关键词 | Cobalt Hexacyanoferrate Ionic Liquid Electrocatalysis Nadh |
| 产权排序 | [Zhang, Qing; Kang, Qi] Shangdong Normal Univ, Coll Chem Chem Engn & Mat Sci, Minist Educ China, Key Lab Mol & Nanomat Probes, Jinan 250014, Peoples R China; [Zhu, Rilong] Hunan Prov Environm Monitoring Ctr, State Environm Protect Key Lab Monitoring Heavy M, Changsha 410014, Hunan, Peoples R China; [Lu, Wenjing; Zhang, Haiyun; Pan, Dawei] Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China; [Lu, Wenjing; Zhang, Haiyun; Pan, Dawei] YICCAS, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China |
| 通讯作者 | Zhang, Q (reprint author), Shangdong Normal Univ, Coll Chem Chem Engn & Mat Sci, Minist Educ China, Key Lab Mol & Nanomat Probes, Jinan 250014, Peoples R China. |
| 作者部门 | 中科院海岸带环境过程与生态修复重点实验室 |
| 英文摘要 | Cobalt hexacyanoferrate particles were ground with water-miscible room-temperature ionic liquid, 1-methylimidazolium trifluoroacetic acidic salts (HMImTfa), and resulted in HMImTfa-CoHCF gel. The electrochemical properties of HMImTfa-CoHCF gel were investigated in detail. The impedance data show that HMImTfa-CoHCF gel is mixed ionic-electronic and has 2.5 times the improvement of the conductivity than that of pure HMImTfa. HMImTfa-CoHCF gel can be used in chemically modified electrode for the electrocatalytic oxidation of NADH. The corresponding results have important implications for the design of nano-structured and nano-composite materials based on water-miscible room-temperature ionic liquids, which could be used widely in chemo/biosensing and catalysis.; Cobalt hexacyanoferrate particles were ground with water-miscible room-temperature ionic liquid, 1-methylimidazolium trifluoroacetic acidic salts (HMImTfa), and resulted in HMImTfa-CoHCF gel. The electrochemical properties of HMImTfa-CoHCF gel were investigated in detail. The impedance data show that HMImTfa-CoHCF gel is mixed ionic-electronic and has 2.5 times the improvement of the conductivity than that of pure HMImTfa. HMImTfa-CoHCF gel can be used in chemically modified electrode for the electrocatalytic oxidation of NADH. The corresponding results have important implications for the design of nano-structured and nano-composite materials based on water-miscible room-temperature ionic liquids, which could be used widely in chemo/biosensing and catalysis. |
| 文章类型 | Article |
| 资助机构 | National Natural Science Foundation of China [21007087]; Chinese Academy of Sciences [KZCX2-YW-JS208]; Natural Science Foundation of Shandong Province [BS2010HZ030]; Taishan Scholar Program of Shandong Province; Youth Innovation Promotion Association of CAS |
| 收录类别 | SCI |
| 语种 | 英语 |
| 关键词[WOS] | WALLED CARBON NANOTUBES ; FILMS ; ELECTROCHEMISTRY |
| 研究领域[WOS] | Electrochemistry |
| WOS记录号 | WOS:000309206900035 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.yic.ac.cn/handle/133337/6078 |
| 专题 | 中国科学院海岸带环境过程与生态修复重点实验室 |
| 作者单位 | 1.Shangdong Normal Univ, Coll Chem Chem Engn & Mat Sci, Minist Educ China, Key Lab Mol & Nanomat Probes, Jinan 250014, Peoples R China 2.Hunan Prov Environm Monitoring Ctr, State Environm Protect Key Lab Monitoring Heavy M, Changsha 410014, Hunan, Peoples R China 3.Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China 4.YICCAS, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Shandong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Qing,Zhu, Rilong,Kang, Qi,et al. Water-Miscible Room-Temperature Ionic Liquid-Cobalt Hexacyanoferrate Gel Modified Electrode for Electrocatalytic Oxidation of NADH[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,2012,7(9):8185-8193. |
| APA | Zhang, Qing,Zhu, Rilong,Kang, Qi,Lu, Wenjing,Zhang, Haiyun,&Pan, Dawei.(2012).Water-Miscible Room-Temperature Ionic Liquid-Cobalt Hexacyanoferrate Gel Modified Electrode for Electrocatalytic Oxidation of NADH.INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,7(9),8185-8193. |
| MLA | Zhang, Qing,et al."Water-Miscible Room-Temperature Ionic Liquid-Cobalt Hexacyanoferrate Gel Modified Electrode for Electrocatalytic Oxidation of NADH".INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 7.9(2012):8185-8193. |
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