Terretonin, ophiobolin, and drimane terpenes with absolute configurations from an algicolous Aspergillus ustus
Liu, Xiang-Hong1; Miao, Feng-Ping1; Qiao, Ming-Feng1; Cichewicz, Robert H.2; Ji, Nai-Yun1
发表期刊RSC ADVANCES
2013
卷号3期号:2页码:588-595
关键词Sesquiterpene
产权排序[Liu, Xiang-Hong; Miao, Feng-Ping; Qiao, Ming-Feng; Ji, Nai-Yun] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China; [Cichewicz, Robert H.] Univ Oklahoma, Norman, OK 73019 USA
通讯作者Liu, XH (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China. nyji@yic.ac.cn
英文摘要One new meroterpene, 1,2-dihydroterretonin F (2), five new sesterterpenes, (6a)-21-deoxyophiobolin G(3), (6a)-16,17-dihydro-21-deoxyophiobolin G (4), phiobolin U (5), ophiobolin V (6), and ophiobolin W (7),two new sesquiterpenes, (6-strobilactone-B) esters of (E,E)-6,7-epoxy-2,4-octadienoic acids (13 and 14),and twelve known terpenes (1, 8–12, and 15–20) were isolated from Aspergillus ustus, a fungus from the fresh tissue of marine green alga Codium fragile. Their structures and absolute configurations were identified by NMR and mass spectroscopic methods as well as quantum chemical calculations. Some of the isolates exhibited antibacterial activity and brine shrimp toxicity.; One new meroterpene, 1,2-dihydroterretonin F (2), five new sesterterpenes, (6 alpha)-21-deoxyophiobolin G (3), (6 alpha)-16,17-dihydro-21-deoxyophiobolin G (4), ophiobolin U (5), ophiobolin V (6), and ophiobolin W(7), two new sesquiterpenes, (6-strobilactone-B) esters of (E,E)-6,7-epoxy-2,4-octadienoic acids (13 and 14), and twelve known terpenes (1, 8-12, and 15-20) were isolated from Aspergillus ustus, a fungus from the fresh tissue of marine green alga Codium fragile. Their structures and absolute configurations were identified by NMR and mass spectroscopic methods as well as quantum chemical calculations. Some of the isolates exhibited antibacterial activity and brine shrimp toxicity.
文章类型Article
资助机构National Natural Science Foundations of China [41106136, 41106137]; Chinese Academy of Sciences for Key Topics in Innovation Engineering [KZCX2-YW-QN209, KSCX2-EW-G-12B]; 12th Five-Year Science and Technology Plan for Agriculture [2012BAD32B09]
收录类别SCI
语种英语
关键词[WOS]SESQUITERPENE
研究领域[WOS]Chemistry
WOS记录号WOS:000312196600040
引用统计
被引频次:48[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/5694
专题海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室
作者单位1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China
2.Univ Oklahoma, Norman, OK 73019 USA
推荐引用方式
GB/T 7714
Liu, Xiang-Hong,Miao, Feng-Ping,Qiao, Ming-Feng,et al. Terretonin, ophiobolin, and drimane terpenes with absolute configurations from an algicolous Aspergillus ustus[J]. RSC ADVANCES,2013,3(2):588-595.
APA Liu, Xiang-Hong,Miao, Feng-Ping,Qiao, Ming-Feng,Cichewicz, Robert H.,&Ji, Nai-Yun.(2013).Terretonin, ophiobolin, and drimane terpenes with absolute configurations from an algicolous Aspergillus ustus.RSC ADVANCES,3(2),588-595.
MLA Liu, Xiang-Hong,et al."Terretonin, ophiobolin, and drimane terpenes with absolute configurations from an algicolous Aspergillus ustus".RSC ADVANCES 3.2(2013):588-595.
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