Colorimetric Detection of Trace Copper Ions Based on Catalytic Leaching of Silver-Coated Gold Nanoparticles
Lou, Tingting1,2,3; Chen, Lingxin1,2; Chen, Zhaopeng1,2; Wang, Yunqing1,2; Chen, Ling1,2,3; Li, Jinhua1,2
发表期刊ACS APPLIED MATERIALS & INTERFACES
ISSN1944-8244
2011-11-01
卷号3期号:11页码:4215-4220
关键词Copper Ions Colorimetric Detection Silver-coated Gold Nanoparticles Catalytic Leaching
产权排序[Lou, Tingting; Chen, Lingxin; Chen, Zhaopeng; Wang, Yunqing; Chen, Ling; Li, Jinhua] CAS, Key Lab Coastal Zone Environm Proc, Yantai 264003, Peoples R China; [Lou, Tingting; Chen, Lingxin; Chen, Zhaopeng; Wang, Yunqing; Chen, Ling; Li, Jinhua] Chinese Acad Sci, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China; [Lou, Tingting; Chen, Ling] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
通讯作者Chen, LX (reprint author), CAS, Key Lab Coastal Zone Environm Proc, Yantai 264003, Peoples R China
作者部门环境化学实验室 
英文摘要A colorimetric, label-free, and nonaggregation-based silver coated gold nanoparticles (Ag/Au NPs) probe has been developed for detection of trace Cu(2+) in aqueous solution, based on the fact that Cu(2+) can accelerate the leaching rate of Ag/Au NPs by thiosulfate (S(2)O(3)(2-)). The leaching of Ag/Au NPs would lead to dramatic decrease in the surface plasmon resonance (SPR) absorption as the size of Ag/Au NPs decreased. This colorimetric strategy based on size-dependence of nanoparticles during their leaching process provided a highly sensitive (1.0 riM) and selective detection toward Cu(2+), with a wide linear detection range (5-800 nM) over nearly 3 orders of magnitude. The cost-effective probe allows rapid and sensitive detection of trace Cu(2+) ions in water samples, indicating its potential applicability for the determination of copper in real samples.; A colorimetric, label-free, and nonaggregation-based silver coated gold nanoparticles (Ag/Au NPs) probe has been developed for detection of trace Cu2+ in aqueous solution, based on the fact that Cu2+ can accelerate the leaching rate of Ag/Au NPs by thiosulfate (S2O32-). The leaching of Ag/Au NPs would lead to dramatic decrease in the surface plasmon resonance (SPR) absorption as the size of Ag/Au NPs decreased. This colorimetric strategy based on size-dependence of nanoparticles during their leaching process provided a highly sensitive (1.0 riM) and selective detection toward Cu2+, with a wide linear detection range (5-800 nM) over nearly 3 orders of magnitude. The cost-effective probe allows rapid and sensitive detection of trace Cu2+ ions in water samples, indicating its potential applicability for the determination of copper in real samples.
文章类型Article
资助机构National Natural Science Foundation of China[20975089, 21105117, 81102415]; Chinese Academy of Sciences[KZCX2-EW-206]; Department of Science and Technology of Shandong Province[2008GG20005005, BS2009DX006]; Department of Science and Technology of Yantai City of China[2007156]
收录类别SCI
语种英语
关键词[WOS]ATOMIC-ABSORPTION-SPECTROMETRY ; HEAVY-METAL IONS ; THIOSULFATE SOLUTIONS ; AU NANOPARTICLES ; CLICK CHEMISTRY ; CU2+ DETECTION ; DISSOLUTION ; HG2+ ; DNA ; PRECONCENTRATION
研究领域[WOS]Science & Technology - Other Topics ; Materials Science
WOS记录号WOS:000297195500010
引用统计
被引频次:145[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/5332
专题中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心
作者单位1.Chinese Acad Sci, Key Lab Coastal Zone Environm Proc, Yantai 264003, Peoples R China
2.Chinese Acad Sci, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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GB/T 7714
Lou, Tingting,Chen, Lingxin,Chen, Zhaopeng,et al. Colorimetric Detection of Trace Copper Ions Based on Catalytic Leaching of Silver-Coated Gold Nanoparticles[J]. ACS APPLIED MATERIALS & INTERFACES,2011,3(11):4215-4220.
APA Lou, Tingting,Chen, Lingxin,Chen, Zhaopeng,Wang, Yunqing,Chen, Ling,&Li, Jinhua.(2011).Colorimetric Detection of Trace Copper Ions Based on Catalytic Leaching of Silver-Coated Gold Nanoparticles.ACS APPLIED MATERIALS & INTERFACES,3(11),4215-4220.
MLA Lou, Tingting,et al."Colorimetric Detection of Trace Copper Ions Based on Catalytic Leaching of Silver-Coated Gold Nanoparticles".ACS APPLIED MATERIALS & INTERFACES 3.11(2011):4215-4220.
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