Ionophore Based Bismuth Film Electrode for Lead | |
Wang, Yuane1,2,3; Pan, Dawei1; Qin, Wei1,4 | |
发表期刊 | ANALYTICAL LETTERS |
2009 | |
卷号 | 42期号:7页码:1000-1013 |
关键词 | Bismuth Film Electrode Ionophore Lead Nafion Stripping Voltammetry |
产权排序 | Chinese Acad Sci, Environm Chem Lab, Yantai Inst Coastal Zone Res Sustainable Dev;Chinese Acad Sci, Inst Oceanol;Chinese Acad Sci, Grad Univ;Yantai Univ, Sch Oceanol |
通讯作者 | Wang, YN, Chinese Acad Sci, Environm Chem Lab, Yantai Inst Coastal Zone Res Sustainable Dev, Yantai 264003, Peoples R China |
作者部门 | 环境化学实验室 |
英文摘要 | A Nafion/ionophore, 4-tert-butylcalix[4]arene-tetrakis(N,N-dimethylthioacetamide) composite coated and bismuth film modified glassy carbon electrode. (GC/NA-IONO/BiFE) was described to determine trace lead sensitively and selectively. The characteristics of such modified GC/NA-IONO/BiFE were studied by scanning electron microscopy and cyclic voltammetry. The influence of various experimental parameters upon the stripping lead signal at the GC/NA-IONO/BiFE was explored. Under the optimized conditions, the differential pulse voltammetric stripping response is highly linear over the 0.1-8.0 nM lead range examined (180s preconcentration at -1.2V), with a detection limit of 0.044nM and good precision (RSD=5.4% at 0.5nM). Also applicability to seawater samples was demonstrated at such modified electrode. The high selectivity of ionophore coupled with the excellent electrochemical characteristics of bismuth endow the GC/NA-IONO/BiFE a promising and robust tool for monitoring of trace lead rapidly and precisely. |
文章类型 | Article |
收录类别 | SCI |
语种 | 英语 |
关键词[WOS] | ANODIC-STRIPPING VOLTAMMETRY ; MERCURY THIN-FILM ; GLASSY-CARBON ELECTRODES ; SCREEN-PRINTED ELECTRODES ; TRACE-METALS ; HEAVY-METALS ; ION-EXCHANGE ; COATINGS ; ELECTROANALYSIS ; SENSORS |
研究领域[WOS] | Chemistry |
WOS记录号 | WOS:000265630700007 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/3437 |
专题 | 中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境过程实验室 |
作者单位 | 1.Chinese Acad Sci, Environm Chem Lab, Yantai Inst Coastal Zone Res Sustainable Dev, Yantai 264003, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Qingdao, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing, Peoples R China 4.Yantai Univ, Sch Oceanol, Yantai, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Yuane,Pan, Dawei,Qin, Wei. Ionophore Based Bismuth Film Electrode for Lead[J]. ANALYTICAL LETTERS,2009,42(7):1000-1013. |
APA | Wang, Yuane,Pan, Dawei,&Qin, Wei.(2009).Ionophore Based Bismuth Film Electrode for Lead.ANALYTICAL LETTERS,42(7),1000-1013. |
MLA | Wang, Yuane,et al."Ionophore Based Bismuth Film Electrode for Lead".ANALYTICAL LETTERS 42.7(2009):1000-1013. |
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