Anodic stripping voltammetric analysis of different species of copper in seawater using an electrochemical sensor | |
Hu, XP; Pan, DW; Han, HT; Wang, CC | |
发表期刊 | JOURNAL OF OCEANOGRAPHY |
ISSN | 0916-8370 |
2019-04 | |
卷号 | 75期号:2页码:149-156 |
关键词 | Voltammetric determination Cu Speciation Seawater Environmental parameters |
研究领域 | Oceanography |
DOI | 10.1007/s10872-018-0491-z |
产权排序 | [Hu, Xueping; Pan, Dawei; Han, Haitao; Wang, Chenchen] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China; [Hu, Xueping; Pan, Dawei; Han, Haitao] Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
作者部门 | 海岸带环境工程技术研究与发展中心 |
英文摘要 | The behavior, effects, and toxicity of an element often depend largely on its speciation. In this study, the speciation of copper (Cu) in seawater was investigated via the fixed-point determination of electroactive Cu, acid-dissolved Cu, inert Cu, and total dissolved Cu using a voltammetric method with an electrochemical sensor. This method was found to be simple and effective for speciation analysis as no complicated pretreatment or separation steps were required, permitting its use for the direct determination of Cu speciation in real water samples with confirmed accuracy. Moreover, following simple electrolytic cleaning, the sensor exhibited good measurement stability and reproducibility when it was reused. Fixed-point determinations of electroactive Cu, acid-dissolved Cu, inert Cu, and total dissolved Cu in local seawater were carried out for 15 days. The total dissolved Cu concentration ranged from 45.03 to 122.85 nM, and its average concentration was 66.05 nM. The speciation of Cu was influenced by external environmental changes to some extent but was observed to remain relatively constant. The correlations between the concentrations of different Cu species and environmental parameters are discussed here in detail. |
文章类型 | Article |
资助机构 | Youth Innovation Promotion Association [2011170] ; Equipment Development Project of the Chinese Academy of Sciences [YZ201558] |
收录类别 | SCI |
语种 | 英语 |
关键词[WOS] | TRACE-METAL ANALYSIS ; ORGANIC-LIGANDS ; ACCURACY RISKS ; NATURAL-WATERS ; SEA-WATER ; SPECIATION ; COMPLEXATION ; CONTAMINATION ; PREVENTION ; TOXICITY |
研究领域[WOS] | Oceanography |
WOS记录号 | WOS:000458908000003 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/24971 |
专题 | 中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心 |
作者单位 | 1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China; 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Hu, XP,Pan, DW,Han, HT,et al. Anodic stripping voltammetric analysis of different species of copper in seawater using an electrochemical sensor[J]. JOURNAL OF OCEANOGRAPHY,2019,75(2):149-156. |
APA | Hu, XP,Pan, DW,Han, HT,&Wang, CC.(2019).Anodic stripping voltammetric analysis of different species of copper in seawater using an electrochemical sensor.JOURNAL OF OCEANOGRAPHY,75(2),149-156. |
MLA | Hu, XP,et al."Anodic stripping voltammetric analysis of different species of copper in seawater using an electrochemical sensor".JOURNAL OF OCEANOGRAPHY 75.2(2019):149-156. |
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