Simultaneous phase-inversion and imprinting based sensor for highly sensitive and selective detection of bisphenol A

doi:10.1016/j.talanta.2017.08.075

	Simultaneous phase-inversion and imprinting based sensor for highly sensitive and selective detection of bisphenol A
	Yang, Qian 1,2; Wu, Xiaqing 1,2; Peng, Hailong 1,4; Fu, Longwen2 ; Song, Xingliang 3; Li, Jinhua2 ; Xiong, Hua 1; Chen, Lingxin2 ; Xiong, Hua(Nanchang Univ, State Key Lab Food Sci & Technol, Nanchang 330047, Jiangxi, Peoples R China); Chen, Lingxin(Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China)
发表期刊	TALANTA
ISSN	0039-9140
	2018
卷号	176 页码:595-603
关键词	Wet Phase Inversion Molecularly Imprinted Films Electrochemical Detection Ti/tio2 Electrode Bisphenol a
研究领域	Chemistry, Analytical
DOI	10.1016/j.talanta.2017.08.075
产权排序	第2完成单位
作者部门	海岸带环境工程技术研究与发展中心
英文摘要	A novel recognition element of molecularly imprinted films (MIFs) was synthesized by wet phase inversion (WPI) on the surface of Ti/TiO2 electrode for highly selective and sensitive electrochemical detection of bisphenol A (BPA). The Ti/TiO2/MIFs sensor was constructed by casting the precursor poly(acrylonitrile-co-acrylic acid) (p(AN-co-AA)) in dimethyl sulfoxide containing template molecule BPA onto the electrode and then immersing into water, resulting in simultaneous p(AN-co-AA) precipitation and BPA imprinting via the facile WPI. The imprinted sites could selectively rebind BPA through hydrogen bonding and hence lead to the equalizing current increase in amperometric detection, by which the BPA could be sensed electrochemically. Accordingly, the Ti/TiO2/MIFs sensor offered a favorable linearity within the wide range over five orders of magnitude (4.4 nM-0.13 mM), and a low detection limit down to 1.3 nM. Excellent recognition selectivity for BPA was also attained over its analogues. Furthermore, this sensor was successfully applied to detect BPA in seawater and paper cup samples, and high recoveries were 86-110% with low relative standard deviations of 1.3-3.2%. By using EPA as a model, the MIFs-based method may provide a facile, rapid, and cost-effective way for ultra sensitive electrochemical measurements of various targeted compounds with good applicability to WPI.
文章类型	Article
资助机构	National Natural Science Foundation of China(21477160, 21667018, 31660482) ; National Defense Science and Technology Innovation Project of Chinese Academy of Sciences(CXJJ-16M254)
收录类别	SCI
语种	英语
关键词[WOS]	ACID COPOLYMER MEMBRANE ; ELECTROCHEMICAL SENSOR ; RECOGNITION ; ELECTRODE ; POLYMERS ; DERIVATIVES ; MATRIX
研究领域[WOS]	Chemistry
WOS记录号	WOS:000412610100075
引用统计	被引频次：45[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/23464
专题	中国科学院海岸带环境过程与生态修复重点实验室中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心
通讯作者	Xiong, Hua; Chen, Lingxin; Xiong, Hua(Nanchang Univ, State Key Lab Food Sci & Technol, Nanchang 330047, Jiangxi, Peoples R China); Chen, Lingxin(Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China)
作者单位	1.Nanchang Univ, State Key Lab Food Sci & Technol, Nanchang 330047, Jiangxi, Peoples R China 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China 3.Linyi Univ, Sch Chem & Chem Engn, Linyi 276005, Peoples R China 4.Nanchang Univ, Sch Resources Environm & Chem Engn, Nanchang 330031, Jiangxi, Peoples R China
推荐引用方式 GB/T 7714	Yang, Qian,Wu, Xiaqing,Peng, Hailong,et al. Simultaneous phase-inversion and imprinting based sensor for highly sensitive and selective detection of bisphenol A[J]. TALANTA,2018,176:595-603.
APA	Yang, Qian.,Wu, Xiaqing.,Peng, Hailong.,Fu, Longwen.,Song, Xingliang.,...&Chen, Lingxin.(2018).Simultaneous phase-inversion and imprinting based sensor for highly sensitive and selective detection of bisphenol A.TALANTA,176,595-603.
MLA	Yang, Qian,et al."Simultaneous phase-inversion and imprinting based sensor for highly sensitive and selective detection of bisphenol A".TALANTA 176(2018):595-603.