YIC-IR  > 中科院海岸带环境过程与生态修复重点实验室
A Systematic Study of the Mass Transport, Kinetic and Thermodynamic Properties of the Fe-III/II Process at Glassy Carbon and Boron-Doped Diamond Electrodes
Lin, Mingyue1,3,4; Li, Jiezhen1; Pan, Dawei3; Bond, Alan M.1,2; Zhang, Jie1,2; Bond, Alan M.(Monash Univ, Sch Chem, Clayton, Vic 3800, Australia); Zhang, Jie(Monash Univ, Sch Chem, Clayton, Vic 3800, Australia)
2017-09-01
Source PublicationELECTROCHIMICA ACTA
ISSN0013-4686
Volume249Pages:421-430
Contribution Rank第3完成单位
AbstractThe heterogeneous electron transfer kinetics (k(0) values), mass transport and thermodynamic properties (E-0 values) associated with the Fe-III/II process have been determined in aqueous solutions containing 0.1 M HCl, HClO4, bis(trifluoromethanesulfonyl) imide (HNTf2) or 0.05 M silicotungstic acid (H-4[alpha-SiW12O40]) supporting electrolytes. The diffusion coefficient (D) values for Fe-III and Fe-II are dependent on the radius of the electrolyte anion and follow the order D(SiW12O404-) < D(NTf2-) < D (ClO4-) < D(Cl-). The k(0) values are found to be smaller at boron doped diamond (BDD) electrodes than glassy carbon (GC) electrodes, and influenced by the ion-pairing between electrolyte anions and FeIII and FeII. Based on the formal potential value, HNTf2 is found to be a more innocent electrolyte than commonly used HClO4 with regard to determine the true k(0) values of the outer-sphere [Fe(H2O)(6)](3+/2+) process. Fourier transformed large amplitude alternating current voltammetry, which provides favorable signal to background ratio, was used to determine k(0) values associated with the Fe-III/II process in H-4[alpha-SiW12O40] and HNTf2 electrolyte media at GC electrodes and probe the implications of the heterogeneity of the BDD electrode surface on the electrode kinetic determination in H-4[alpha-SiW12O40] electrolyte media. (C) 2017 Elsevier Ltd. All rights reserved.
KeywordFe-iii/ii Process Electron Transfer Kinetics Fourier Transformed Alternating Current Voltammetry Medium Effect Electrode Heterogeneity
DOI10.1016/j.electacta.2017.07.155
Funding OrganizationUniversity of Chinese Academy of Sciences ; Monash University ; Australian Research Council
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Indexed BySCI ; ISTP
WOS KeywordTHIN-FILM ELECTRODES ; ALTERNATING-CURRENT VOLTAMMETRY ; CYCLIC VOLTAMMETRY ; IONIC LIQUIDS ; ELECTROCHEMICAL-BEHAVIOR ; DISK ELECTRODE ; REDOX COUPLE ; SURFACE ; REDUCTION ; CHEMISTRY
SubtypeArticle
Language英语
WOS Research AreaElectrochemistry
WOS IDWOS:000410675100048
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.yic.ac.cn/handle/133337/23435
Collection中科院海岸带环境过程与生态修复重点实验室
Corresponding AuthorBond, Alan M.; Zhang, Jie; Bond, Alan M.(Monash Univ, Sch Chem, Clayton, Vic 3800, Australia); Zhang, Jie(Monash Univ, Sch Chem, Clayton, Vic 3800, Australia)
Affiliation1.Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
2.Monash Univ, ARC Ctr Excellence Electrochem Sci, Clayton, Vic 3800, Australia
3.Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Shandong Prov Key Lab Coastal Environm Proc,YICCA, Yantai 264003, Shandong, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
First Author AffilicationYantai Institute of Coastal Zone Research, Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Lin, Mingyue,Li, Jiezhen,Pan, Dawei,et al. A Systematic Study of the Mass Transport, Kinetic and Thermodynamic Properties of the Fe-III/II Process at Glassy Carbon and Boron-Doped Diamond Electrodes[J]. ELECTROCHIMICA ACTA,2017,249:421-430.
APA Lin, Mingyue.,Li, Jiezhen.,Pan, Dawei.,Bond, Alan M..,Zhang, Jie.,...&Zhang, Jie.(2017).A Systematic Study of the Mass Transport, Kinetic and Thermodynamic Properties of the Fe-III/II Process at Glassy Carbon and Boron-Doped Diamond Electrodes.ELECTROCHIMICA ACTA,249,421-430.
MLA Lin, Mingyue,et al."A Systematic Study of the Mass Transport, Kinetic and Thermodynamic Properties of the Fe-III/II Process at Glassy Carbon and Boron-Doped Diamond Electrodes".ELECTROCHIMICA ACTA 249(2017):421-430.
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