Synthesis, characterization, and antifungal evaluation of novel 1,2,3-triazolium-functionalized starch derivative
Tan, Wenqiang1,2; Zhang, Jingjing1,2; Luan, Fang1,2; Wei, Lijie1,2; Li, Qing1; Dong, Fang1; Guo, Zhanyong1,2
发表期刊INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
ISSN0141-8130
2017-08-01
卷号101页码:845-851
关键词Starch Derivative Functional Antifungal Activity 1 Biomaterial 2 Benzyl Bromide 3-triazolium
研究领域Biochemistry & Molecular Biology ; Chemistry, Applied ; Polymer Science
DOI10.1016/j.ijbiomac.2017.03.171
产权排序[Tan, Wenqiang; Zhang, Jingjing; Luan, Fang; Wei, Lijie; Li, Qing; Dong, Fang; Guo, Zhanyong] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China; [Tan, Wenqiang; Zhang, Jingjing; Luan, Fang; Wei, Lijie; Guo, Zhanyong] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
作者部门海岸带生物资源高效利用研究与发展中心
英文摘要1,2,3-Triazolium-functionalized starch derivative was obtained by straightforward quaternization of the synthesized starch derivative bearing 1,2,3-triazole with benzyl bromide by combining the robust attributes of cuprous-catalyzed azide-alkyne cycloaddition. These novel starch derivatives were characterized by FTIR, UV-vis, H-1 NMR, C-13 NMR, and elemental analysis. Their antifungal activities against Colletotrichum lagenarium, Watermelon fusarium, and Phomopsis asparagi were investigated by hypha measurement in vitro. The fungicidal assessment revealed that compared with starch and starch derivative bearing 1,2,3-triazole with inhibitory indices of below 15% at 1.0 mg/mL, 1,2,3-triazolium-functionalized starch derivative had superior antifungal activity with inhibitory rates of over 60%. Especially, the best inhibitory index of 1,2,3-triazolium-functionalized starch derivative against Colletotrichum lagenarium attained 90% above at 1.0mg/mL. The results obviously showed that quaternization of 1,2,3-triazole with benzyl bromide could effectively enhance antifungal activity of the synthesized starch derivatives. The synthetic strategy described here could be utilized for the development of starch as novel antifungal biomaterial. (C) 2017 Elsevier B.V. All rights reserved.
文章类型Article
资助机构National Natural Science Foundation of China(41576156) ; Shandong Province Science and Technology Development Plan(2015GSF121045) ; Yantai Science and Technology Development Plan(2015ZH078) ; Public Science and Technology Research Funds Projects of Ocean(201505022-3)
收录类别SCI
语种英语
关键词[WOS]ANTIBACTERIAL ACTIVITY ; CLICK CHEMISTRY ; RHEOLOGICAL PROPERTIES ; CHITOSAN ; CELLULOSE ; PROPERTY ; LIQUID)S ; DESIGN ; INULIN ; FILMS
研究领域[WOS]Biochemistry & Molecular Biology ; Chemistry ; Polymer Science
WOS记录号WOS:000404491300094
引用统计
被引频次:24[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/22551
专题海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室
中国科学院海岸带环境过程与生态修复重点实验室_污染过程与控制实验室
海岸带生物学与生物资源利用重点实验室_海岸带生物资源高效利用研究与发展中心
作者单位1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Tan, Wenqiang,Zhang, Jingjing,Luan, Fang,et al. Synthesis, characterization, and antifungal evaluation of novel 1,2,3-triazolium-functionalized starch derivative[J]. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,2017,101:845-851.
APA Tan, Wenqiang.,Zhang, Jingjing.,Luan, Fang.,Wei, Lijie.,Li, Qing.,...&Guo, Zhanyong.(2017).Synthesis, characterization, and antifungal evaluation of novel 1,2,3-triazolium-functionalized starch derivative.INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,101,845-851.
MLA Tan, Wenqiang,et al."Synthesis, characterization, and antifungal evaluation of novel 1,2,3-triazolium-functionalized starch derivative".INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES 101(2017):845-851.
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