Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
Optical Ion Sensing Platform Based on Potential-Modulated Release of Enzyme | |
Ding, Jiawang; Lv, Enguang; Zhu, Liyan; Qin, Wei1; Qin, W (reprint author), Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Yantai 264003, Shandong, Peoples R China. wqin@yic.ac.cn | |
发表期刊 | ANALYTICAL CHEMISTRY |
ISSN | 0003-2700 |
2017-03-21 | |
卷号 | 89期号:6页码:3235-3239 |
关键词 | Electrogenerated Chemiluminescence Potentiometric Sensors Selective Electrodes Membrane Electrodes Gold Nanoparticles Optodes Heparin Systems |
DOI | 10.1021/acs.analchem.7b00072 |
产权排序 | [Qin, Wei] Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Yantai 264003, Shandong, Peoples R China; YICCAS, Shandong Prov Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China |
作者部门 | 中科院海岸带环境过程与生态修复重点实验室 |
英文摘要 | We report here on an optical ion sensing platform, in which a polymeric membrane ion-selective electrode (ISE) serves as not only a potentiometric transducer for ion activities in the sample solution but also a reference electrode for the potential-modulated release of enzyme from an iron alginate-horseradish peroxidase (HRP) thin film modified working electrode. The ISE and working electrode are physically separated by a salt bridge: The dissolution of the HRP-embedded thin film can be triggered by the reduction of Fe3+, which is modulated by the potential response of the ISE to the target ion in the sample. The released enzyme induces the, oxidation of its substrate mediated by H2O2, to produce a visual color change. With this setup, an optical ion sensing platform for both cations (e.g., NH4+) and anions,(e.g., Cl-) can be obtained. The proposed platform provides a general and versatile visual-sensing strategy for ions and allows optical ion sensing in colored and turbid solutions. |
文章类型 | Article |
资助机构 | National Natural Science Foundation of China(21575158 ; Strategic Priority Research Program of the Chinese Academy of Sciences(XDA11020702) ; Youth Innovation Promotion Association of CAS(2013139) ; Taishan Scholar Program of Shandong Province(TS20081159) ; 21475148) |
收录类别 | SCI |
语种 | 英语 |
关键词[WOS] | ELECTROGENERATED CHEMILUMINESCENCE ; POTENTIOMETRIC SENSORS ; SELECTIVE ELECTRODES ; MEMBRANE ELECTRODES ; GOLD NANOPARTICLES ; OPTODES ; HEPARIN ; SYSTEMS |
研究领域[WOS] | Chemistry |
WOS记录号 | WOS:000397478300001 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/22062 |
专题 | 中国科学院海岸带环境过程与生态修复重点实验室 |
通讯作者 | Qin, W (reprint author), Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Yantai 264003, Shandong, Peoples R China. wqin@yic.ac.cn |
作者单位 | 1.Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Yantai 264003, Shandong, Peoples R China 2.YICCAS, Shandong Prov Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China |
推荐引用方式 GB/T 7714 | Ding, Jiawang,Lv, Enguang,Zhu, Liyan,et al. Optical Ion Sensing Platform Based on Potential-Modulated Release of Enzyme[J]. ANALYTICAL CHEMISTRY,2017,89(6):3235-3239. |
APA | Ding, Jiawang,Lv, Enguang,Zhu, Liyan,Qin, Wei,&Qin, W .(2017).Optical Ion Sensing Platform Based on Potential-Modulated Release of Enzyme.ANALYTICAL CHEMISTRY,89(6),3235-3239. |
MLA | Ding, Jiawang,et al."Optical Ion Sensing Platform Based on Potential-Modulated Release of Enzyme".ANALYTICAL CHEMISTRY 89.6(2017):3235-3239. |
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