An effective solid contact for an all-solid-state polymeric membrane Cd2+-selective electrode: Three-dimensional porous graphene-mesoporous platinum nanoparticle composite
Li, Jinghui1,2; Yin, Tanji1; Qin, Wei1
发表期刊SENSORS AND ACTUATORS B-CHEMICAL
ISSN0925-4005
2017-02-01
卷号239页码:438-446
关键词Three-dimensional Porous Graphene Mesoporous Platinum Nanoparticles Solid Contact All-solid-state Ion-selective Electrode Cadmium
DOI10.1016/j.snb.2016.08.008
作者部门中科院海岸带环境过程与生态修复重点实验室
英文摘要

The three-dimensional porous graphene-mesoporous platinum nanoparticle (3D PGR-MPN) composite is used as solid contact for developing an all-solid-state polymeric membrane Cd2+ ion-selective electrode (Cd2+-ISE). The 3D PGR with MPNs as cross-linking sites can be synthesized by a facile hydrothermal co-assembly method. The obtained 3D PGR-MPN composite is promising for acting as solid contact due to its unique characteristics such as high interfacial area, superior double layer capacitance, excellent conductivity and high hydrophobicity. The ISE exhibits a stable Nernstian response in the range of 10(-8)-10(-4) M and the detection limit is 10(-8.8) M. The 3D PGR-MPN-based Cd2+-ISE shows good potential response and no water layer exists between the polymeric membrane and the 3D PGR-MPN layer. Additionally, the proposed Cd2+-ISE is robust to O-2, CO2 and light interferences. This work provides a versatile method for preparing an effective solid contact to develop a stable and reliable all- solid-state ISE. (C) 2016 Elsevier B.V. All rights reserved.

文章类型Article
资助机构Strategic Priority Research Program of the Chinese Academy of Sciences(XDA11020702) ; National Natural Science Foundation of China(21475148) ; Natural Science Foundation of Shandong Province(ZR2014BQ006) ; Taishan Scholar Program of Shandong Province ; Science and Technology Project of Yantai City(2015ZH088)
收录类别SCI
语种英语
关键词[WOS]ION-SELECTIVE ELECTRODES ; ONE-POT SYNTHESIS ; POTENTIOMETRIC SENSORS ; PB2+-SELECTIVE ELECTRODE ; HYBRID ARCHITECTURES ; CONDUCTING POLYMERS ; CARBON-BLACK ; TRANSDUCERS ; HYDROGEL ; FILMS
研究领域[WOS]Chemistry ; Electrochemistry ; Instruments & Instrumentation
WOS记录号WOS:000388951300054
引用统计
被引频次:31[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/19260
专题中国科学院海岸带环境过程与生态修复重点实验室
通讯作者Yin, Tanji
作者单位1.Chinese Acad Sci, Key Lab Coastal Environm Processes & Ecol Remedia, Yantai Inst Coastal Zone Res YIC, Shandong Prov Key Lab Coastal Environm Proc,YICCA, Yantai 264003, Shandong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Li, Jinghui,Yin, Tanji,Qin, Wei. An effective solid contact for an all-solid-state polymeric membrane Cd2+-selective electrode: Three-dimensional porous graphene-mesoporous platinum nanoparticle composite[J]. SENSORS AND ACTUATORS B-CHEMICAL,2017,239:438-446.
APA Li, Jinghui,Yin, Tanji,&Qin, Wei.(2017).An effective solid contact for an all-solid-state polymeric membrane Cd2+-selective electrode: Three-dimensional porous graphene-mesoporous platinum nanoparticle composite.SENSORS AND ACTUATORS B-CHEMICAL,239,438-446.
MLA Li, Jinghui,et al."An effective solid contact for an all-solid-state polymeric membrane Cd2+-selective electrode: Three-dimensional porous graphene-mesoporous platinum nanoparticle composite".SENSORS AND ACTUATORS B-CHEMICAL 239(2017):438-446.
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