Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
An effective solid contact for an all-solid-state polymeric membrane Cd2+-selective electrode: Three-dimensional porous graphene-mesoporous platinum nanoparticle composite | |
Li, Jinghui1,2; Yin, Tanji1; Qin, Wei1 | |
发表期刊 | SENSORS AND ACTUATORS B-CHEMICAL |
ISSN | 0925-4005 |
2017-02-01 | |
卷号 | 239页码:438-446 |
关键词 | Three-dimensional Porous Graphene Mesoporous Platinum Nanoparticles Solid Contact All-solid-state Ion-selective Electrode Cadmium |
DOI | 10.1016/j.snb.2016.08.008 |
作者部门 | 中科院海岸带环境过程与生态修复重点实验室 |
英文摘要 | The three-dimensional porous graphene-mesoporous platinum nanoparticle (3D PGR-MPN) composite is used as solid contact for developing an all-solid-state polymeric membrane Cd2+ ion-selective electrode (Cd2+-ISE). The 3D PGR with MPNs as cross-linking sites can be synthesized by a facile hydrothermal co-assembly method. The obtained 3D PGR-MPN composite is promising for acting as solid contact due to its unique characteristics such as high interfacial area, superior double layer capacitance, excellent conductivity and high hydrophobicity. The ISE exhibits a stable Nernstian response in the range of 10(-8)-10(-4) M and the detection limit is 10(-8.8) M. The 3D PGR-MPN-based Cd2+-ISE shows good potential response and no water layer exists between the polymeric membrane and the 3D PGR-MPN layer. Additionally, the proposed Cd2+-ISE is robust to O-2, CO2 and light interferences. This work provides a versatile method for preparing an effective solid contact to develop a stable and reliable all- solid-state ISE. (C) 2016 Elsevier B.V. All rights reserved. |
文章类型 | Article |
资助机构 | Strategic Priority Research Program of the Chinese Academy of Sciences(XDA11020702) ; National Natural Science Foundation of China(21475148) ; Natural Science Foundation of Shandong Province(ZR2014BQ006) ; Taishan Scholar Program of Shandong Province ; Science and Technology Project of Yantai City(2015ZH088) |
收录类别 | SCI |
语种 | 英语 |
关键词[WOS] | ION-SELECTIVE ELECTRODES ; ONE-POT SYNTHESIS ; POTENTIOMETRIC SENSORS ; PB2+-SELECTIVE ELECTRODE ; HYBRID ARCHITECTURES ; CONDUCTING POLYMERS ; CARBON-BLACK ; TRANSDUCERS ; HYDROGEL ; FILMS |
研究领域[WOS] | Chemistry ; Electrochemistry ; Instruments & Instrumentation |
WOS记录号 | WOS:000388951300054 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/19260 |
专题 | 中国科学院海岸带环境过程与生态修复重点实验室 |
通讯作者 | Yin, Tanji |
作者单位 | 1.Chinese Acad Sci, Key Lab Coastal Environm Processes & Ecol Remedia, Yantai Inst Coastal Zone Res YIC, Shandong Prov Key Lab Coastal Environm Proc,YICCA, Yantai 264003, Shandong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Jinghui,Yin, Tanji,Qin, Wei. An effective solid contact for an all-solid-state polymeric membrane Cd2+-selective electrode: Three-dimensional porous graphene-mesoporous platinum nanoparticle composite[J]. SENSORS AND ACTUATORS B-CHEMICAL,2017,239:438-446. |
APA | Li, Jinghui,Yin, Tanji,&Qin, Wei.(2017).An effective solid contact for an all-solid-state polymeric membrane Cd2+-selective electrode: Three-dimensional porous graphene-mesoporous platinum nanoparticle composite.SENSORS AND ACTUATORS B-CHEMICAL,239,438-446. |
MLA | Li, Jinghui,et al."An effective solid contact for an all-solid-state polymeric membrane Cd2+-selective electrode: Three-dimensional porous graphene-mesoporous platinum nanoparticle composite".SENSORS AND ACTUATORS B-CHEMICAL 239(2017):438-446. |
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