Synthesis and catalytic performance of Al-MCM-48 and Ti-MCM-48
Zhixi, Zhao1; Zhang, Liming1; Chen, Ping1; Kun, Yan2
发表期刊Open Materials Science Journal
ISSN1874-088X
2015
卷号9页码:194-197
关键词Aluminum Catalyst Activity Phase Transitions Styrene Titanium Al-mcm-48 Catalytic Performance Conversion Rates Hydrothermal Methods Styrene Oxidation Ti-mcm-48 Titanium Source Transalkylation
产权排序(1) Key Laboratory of Pollution Monitoring and Control, Xinjiang Normal University, Urumqi; 830054, China; (2) Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai; Shandong; 264003, China
作者部门中科院海岸带环境过程与生态修复重点实验室
英文摘要Mesoporous sieves MCM-48 with hetero atom were synthesized by adding aluminum and titanium sources through hydrothermal method. The results showed that MCM-48 could be synthesized respectively by adjusting exactly the alkalinity of synthesis gel. The conversion rate of DIPB on Al-MCM-48 increased to 80% after 9 h and the selectivity of IPB was were 97%. The conversion rate of styrene on Ti-MCM-48 increased to 9% after 8 h and the selectivity of benzaldehyde was 85%. The available active sites, which were introduced by aluminum and titanium atoms, were effectively utilized for catalyst reaction due to the presence of mesopores in Al-MCM-48 and Ti-MCM-48.
文章类型Journal article
语种英语
研究领域[WOS]Titanium and Alloys ; Physical Chemistry ; Chemical Agents and Basic Industrial Chemicals ; Chemical Products Generally ; Organic Compounds
WOS记录号WOS:1
引用统计
文献类型期刊论文
条目标识符http://ir.yic.ac.cn/handle/133337/17494
专题中国科学院海岸带环境过程与生态修复重点实验室
通讯作者Kun, Yan
作者单位1. Key Laboratory of Pollution Monitoring and Control, Xinjiang Normal University
2. Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences
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GB/T 7714
Zhixi, Zhao,Zhang, Liming,Chen, Ping,et al. Synthesis and catalytic performance of Al-MCM-48 and Ti-MCM-48[J]. Open Materials Science Journal,2015,9:194-197.
APA Zhixi, Zhao,Zhang, Liming,Chen, Ping,&Kun, Yan.(2015).Synthesis and catalytic performance of Al-MCM-48 and Ti-MCM-48.Open Materials Science Journal,9,194-197.
MLA Zhixi, Zhao,et al."Synthesis and catalytic performance of Al-MCM-48 and Ti-MCM-48".Open Materials Science Journal 9(2015):194-197.
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