Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
Synthesis and catalytic performance of Al-MCM-48 and Ti-MCM-48 | |
Zhixi, Zhao1; Zhang, Liming1; Chen, Ping1; Kun, Yan2 | |
发表期刊 | Open Materials Science Journal |
ISSN | 1874-088X |
2015 | |
卷号 | 9页码:194-197 |
关键词 | Aluminum Catalyst Activity Phase Transitions Styrene Titanium Al-mcm-48 Catalytic Performance Conversion Rates Hydrothermal Methods Styrene Oxidation Ti-mcm-48 Titanium Source Transalkylation |
产权排序 | (1) Key Laboratory of Pollution Monitoring and Control, Xinjiang Normal University, Urumqi; 830054, China; (2) Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai; Shandong; 264003, China |
作者部门 | 中科院海岸带环境过程与生态修复重点实验室 |
英文摘要 | Mesoporous sieves MCM-48 with hetero atom were synthesized by adding aluminum and titanium sources through hydrothermal method. The results showed that MCM-48 could be synthesized respectively by adjusting exactly the alkalinity of synthesis gel. The conversion rate of DIPB on Al-MCM-48 increased to 80% after 9 h and the selectivity of IPB was were 97%. The conversion rate of styrene on Ti-MCM-48 increased to 9% after 8 h and the selectivity of benzaldehyde was 85%. The available active sites, which were introduced by aluminum and titanium atoms, were effectively utilized for catalyst reaction due to the presence of mesopores in Al-MCM-48 and Ti-MCM-48. |
文章类型 | Journal article |
语种 | 英语 |
研究领域[WOS] | Titanium and Alloys ; Physical Chemistry ; Chemical Agents and Basic Industrial Chemicals ; Chemical Products Generally ; Organic Compounds |
WOS记录号 | WOS:1 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.yic.ac.cn/handle/133337/17494 |
专题 | 中国科学院海岸带环境过程与生态修复重点实验室 |
通讯作者 | Kun, Yan |
作者单位 | 1. Key Laboratory of Pollution Monitoring and Control, Xinjiang Normal University 2. Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences |
推荐引用方式 GB/T 7714 | Zhixi, Zhao,Zhang, Liming,Chen, Ping,et al. Synthesis and catalytic performance of Al-MCM-48 and Ti-MCM-48[J]. Open Materials Science Journal,2015,9:194-197. |
APA | Zhixi, Zhao,Zhang, Liming,Chen, Ping,&Kun, Yan.(2015).Synthesis and catalytic performance of Al-MCM-48 and Ti-MCM-48.Open Materials Science Journal,9,194-197. |
MLA | Zhixi, Zhao,et al."Synthesis and catalytic performance of Al-MCM-48 and Ti-MCM-48".Open Materials Science Journal 9(2015):194-197. |
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