Synthesis, characterization, and antifungal property of chitosan ammonium salts with halogens

doi:10.1016/j.ijbiomac.2016.07.023

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	Synthesis, characterization, and antifungal property of chitosan ammonium salts with halogens
	Tan, WQ; Li, Q; Dong, F; Wei, LJ; Guo, ZY; Guo, ZY (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China. Email:zhanyongguo@hotmail.com
发表期刊	INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
ISSN	0141-8130
	2016-11-01
卷号	92 页码:293-298
关键词	Chitosan Ammonium Salts Antifungal Activity Group Electronegativity
DOI	10.1016/j.ijbiomac.2016.07.023
产权排序	[Tan, Wenqiang; Li, Qing; Dong, Fang; Wei, Lijie; Guo, Zhanyong] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China; [Tan, Wenqiang; Wei, Lijie] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
作者部门	海岸带生物学与生物资源利用所重点实验室
英文摘要	In this study, a group of novel water soluble chitosan ammonium salts with halogens were successfully synthesized, including chitosan-bromoacetate (CSB), chitosan-chloroacetate (CSC), chitosan-dichloroacetate (CSDC), chitosan-trichloroacetate (CSTC), and chitosan-trifluoroacetate (CSTF), and their antifungal activities against three kinds of phytopathogens were comparatively estimated by hypha measurement in vitro, respectively. The fungicidal assessment revealed that the synthesized chitosan derivatives had higher antifungal activity than chitosan. Especially, the inhibitory indices of CSTC and CSTF against three kinds of phytopathogens were higher than 70% at 1.0 mg/mL. Generally, the antifungal activity decreased in the order: CSTF > CSTC > CSDC > CSC > CSB > chitosan. Apparently, the order of antifungal activity was consistent with the electronegativity of different substituted groups with halogens. The substituted groups with stronger electronegativity could augment the positive charge densities of cationic amino groups by drawing more electrons from the cationic amino groups of chitosan ammonium salts, which demonstrated that the protonation of amino groups was significant for the antifungal activity of chitosan derivatives. (C) 2016 Elsevier B.V. All rights reserved.
文章类型	Article
资助机构	National Natural Science Foundation of China(41576156) ; Shandong Province Science and Technology Development Plan(2015GSF121045) ; Yantai Science and Technology Development Plan(2015ZH078) ; Public Science and Technology Research Funds Projects of Ocean(201505022-3)
收录类别	SCI
语种	英语
关键词[WOS]	RADICALS SCAVENGING ACTIVITY ; PLANT-PATHOGENIC BACTERIA ; N-SUBSTITUTED CHITOSAN ; QUATERNIZED CHITOSAN ; GREEN SYNTHESIS ; DRUG-DELIVERY ; SHELF-LIFE ; DERIVATIVES ; ANTIOXIDANT ; OPPORTUNITIES
研究领域[WOS]	Biochemistry & Molecular Biology ; Chemistry ; Polymer Science
WOS记录号	WOS:000386402900036
引用统计	被引频次：43[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.yic.ac.cn/handle/133337/17465
专题	海岸带生物学与生物资源利用重点实验室_海岸带生物学与生物资源保护实验室中国科学院海岸带环境过程与生态修复重点实验室_污染过程与控制实验室海岸带生物学与生物资源利用重点实验室_海岸带生物资源高效利用研究与发展中心
通讯作者	Guo, ZY (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Bioresource Utilizat, Yantai 264003, Peoples R China. Email:zhanyongguo@hotmail.com
推荐引用方式 GB/T 7714	Tan, WQ,Li, Q,Dong, F,et al. Synthesis, characterization, and antifungal property of chitosan ammonium salts with halogens[J]. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,2016,92:293-298.
APA	Tan, WQ,Li, Q,Dong, F,Wei, LJ,Guo, ZY,&Guo, ZY .(2016).Synthesis, characterization, and antifungal property of chitosan ammonium salts with halogens.INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,92,293-298.
MLA	Tan, WQ,et al."Synthesis, characterization, and antifungal property of chitosan ammonium salts with halogens".INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES 92(2016):293-298.

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