Institutional Repository of Key Laboratory of Coastal Zone Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences (KLCEP)
| Rapid and sensitive determination of cobalt by adsorptive cathodic stripping voltammetry using tin-bismuth alloy electrode | |
Zhang, L ; Pan, DW; Liu, YS; Liu, YS (reprint author), Peking Univ, Coll Environm Sci & Engn, Beijing 100871, Peoples R China. yshliu@pku.edu.cn
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| 发表期刊 | IONICS
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| ISSN | 0947-7047 |
| 2016-05-01 | |
| 卷号 | 22期号:5页码:721-729 |
| 关键词 | Tin-bismuth Alloy Electrode Adsorptive Cathodic Stripping Voltammetry Cobalt Tap Water |
| DOI | 10.1007/s11581-015-1596-7 |
| 产权排序 | [Zhang, Li; Liu, Yang-sheng] Peking Univ, Coll Environm Sci & Engn, Beijing 100871, Peoples R China; [Pan, Da-wei] Chinese Acad Sci, Yantai 264003, Peoples R China; [Pan, Da-wei] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Shandong Prov Key Lab Coastal Zone Environm Proc, Yantai 264003, Peoples R China |
| 作者部门 | 中科院海岸带环境过程与生态修复重点实验室 |
| 英文摘要 | Tin-bismuth alloy electrode (SnBiE) was used for trace cobalt determination for the first time. Compared to the bismuth bulk electrode, the SnBiE possesses the advantages of higher hydrogen overpotential, easier manufacture, and lower cost. In addition, there is no need for a pretreatment (in terms of modification) of the electrode before measurements. The analysis of Co(II) was made by the adsorptive accumulation of the cobalt-nioxime complex from solution containing 60 mu M nioxime and 0.1 M ammonia at pH 9.4 and followed by the reduction of the accumulated complex. The electroanalysis results show that the optimal sensitivity can be obtained by using nitrite as the auxiliary reagent. The calibration plot for Co(II) quantification was linear from 0.2 to 20 nM with a correlation coefficient of 0.998. Meanwhile, a detection limit of 44 pM was obtained in connection with an accumulation time of 60 s, which is more sensitive than that of the mercury, bismuth, lead, and lead-copper electrodes. The practical applications of SnBiE have been performed for the determination of Co(II) in real water samples, and the results are consistent with those results by use of inductively coupled plasma-mass spectrometry (ICP-MS). |
| 文章类型 | Article |
| 收录类别 | SCI |
| 语种 | 英语 |
| 关键词[WOS] | AMALGAM FILM ELECTRODE ; CLOUD POINT EXTRACTION ; LEAD FILM ; PYROGALLOL RED ; BULK ELECTRODE ; NICKEL ; TRACE ; SYSTEMS ; PRECONCENTRATION ; SPECTROMETRY |
| 研究领域[WOS] | Chemistry ; Electrochemistry ; Physics |
| WOS记录号 | WOS:000374675000013 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.yic.ac.cn/handle/133337/17070 |
| 专题 | 中国科学院海岸带环境过程与生态修复重点实验室 中国科学院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心 中国科学院烟台海岸带研究所知识产出 |
| 通讯作者 | Liu, YS (reprint author), Peking Univ, Coll Environm Sci & Engn, Beijing 100871, Peoples R China. yshliu@pku.edu.cn |
| 作者单位 | 1.Peking Univ, Coll Environm Sci & Engn 2.Chinese Acad Sci 3.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Shandong Prov Key Lab Coastal Zone Environm Proc |
| 推荐引用方式 GB/T 7714 | Zhang, L,Pan, DW,Liu, YS,et al. Rapid and sensitive determination of cobalt by adsorptive cathodic stripping voltammetry using tin-bismuth alloy electrode[J]. IONICS,2016,22(5):721-729. |
| APA | Zhang, L,Pan, DW,Liu, YS,&Liu, YS .(2016).Rapid and sensitive determination of cobalt by adsorptive cathodic stripping voltammetry using tin-bismuth alloy electrode.IONICS,22(5),721-729. |
| MLA | Zhang, L,et al."Rapid and sensitive determination of cobalt by adsorptive cathodic stripping voltammetry using tin-bismuth alloy electrode".IONICS 22.5(2016):721-729. |
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| Rapid and sensitive （608KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 | |
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